4.7 Review

Reduction of acid mine drainage by passivation of pyrite surfaces: A review

Journal

SCIENCE OF THE TOTAL ENVIRONMENT
Volume 832, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.scitotenv.2022.155116

Keywords

Acid mine drainage; Pyrite; Surface passivation; Pollution prevention technology; Environmental protection

Funding

  1. National Nature Science Foundation of China [41807367]
  2. Guangxi Science and Technology Planning Project [2018GXNSFBA050001, GuiKE-AD19245065, Guike-AD19110105]
  3. Program for High Level Innovation Team and Out-standing Scholar of Universities in Guangxi [[2018] 319]

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Acid mine drainage (AMD) is a significant source of environmental pollution globally, and the conventional methods for its remedial treatment are costly and may lead to secondary pollution. This review highlights the importance of pyrite surface passivation as a potential solution to prevent or reduce AMD generation and associated pollution. Various pyrite anti-corrosion technologies, including inorganic, organic, and organosilane passivating coatings, are summarized. The need for future research to integrate existing passivation agents or new artificial materials while considering environmental conditions, costs, and long-term passivation performance is emphasized.
Acid mine drainage (AMD), a source of considerable environmental pollution worldwide, has prompted the development of many strategies to alleviate its effects. Unfortunately, the methods available for remedial treatment of AMD and the damage it cause are generally costly, labor-intensive, and time-consuming. Furthermore, such treatments may result in secondary pollution. Alternatively, treating the AMD problem at its source through pyrite surface passivation has become an important topic for research because it has the potential to reduce or prevent the generation of AMD and associated pollution. This review summarizes various pyrite anti-corrosion technologies, including the formation of various passivating coatings (inorganic, organic and organosilane) and carrier-microencapsulation. Several effective long-term passivators are identified, although many of them currently have important deficiencies that limit their practical application. Combining the mechanisms of existing passivation agents or new artificial materials, while considering environmental conditions, costs, and long-term passivation performance, is a feasible direction for future research.

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