4.8 Article

A dry ancient plume mantle from noble gas isotopes

Publisher

NATL ACAD SCIENCES
DOI: 10.1073/pnas.2201815119

Keywords

volatiles; xenon; noble gases; plume; heterogeneity

Funding

  1. Department of Energy National Nuclear Security Administration [DENA003911]

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Primordial volatiles were delivered to the Earth's mantle during its formation. This study used isotopic ratios to determine the proportions of volatile elements in the mantle plume and upper mantle, finding that the plume mantle had lower concentrations of volatiles compared to the upper mantle at the end of formation. This finding is crucial for understanding the noble gas signatures in mantle rocks.
Primordial volatiles were delivered to terrestrial reservoirs during Earth's accretion, and the mantle plume source is thought to have retained a greater proportion of primordial volatiles compared with the upper mantle. This study shows that mantle He, Ne, and Xe isotopes require that the plume mantle had low concentrations of volatiles like Xe and H2O at the end of accretion compared with the upper mantle. A lower extent of mantle processing alone is not sufficient to explain plume noble gas signatures. Ratios of primordial isotopes are used to determine proportions of solar, chondritic, and regassed atmospheric volatiles in the plume mantle and upper mantle. The regassed Ne flux exceeds the regassed Xe flux but has a small impact on the mantle Ne budget. Pairing primordial isotopes with radiogenic systems gives an absolute concentration of Xe-130 in the plume source of similar to 1.5 x 10(7) atoms Xe-130/g at the end of accretion, similar to 4 times less than that determined for the ancient upper mantle. A record of limited accretion of volatile-rich solids thus survives in the He-Ne-Xe signatures of mantle rocks today. A primordial viscosity contrast originating from a factor of similar to 4 to similar to 250 times lower H2O concentration in the plume mantle compared with the upper mantle may explain (a) why giant impacts that triggered whole mantle magma oceans did not homogenize the growing planet, (b) why the plume mantle has experienced less processing by partial melting over Earth's history, and (c) how early-formed isotopic heterogeneities may have survived similar to 4.5 Gy of solid-state mantle convection.

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