Stability and Rupture of an Ultrathin Ionic Wire

Using a combination of in situ high-resolution transmission electron microscopy and density functional theory, we report the formation and rupture of ZrO2 atomic ionic wires. Near rupture, under tensile stress, the system favors the spontaneous formation of oxygen vacancies, a critical step in the formation of the monatomic bridge. In this length scale, vacancies provide ductilelike behavior, an unexpected mechanical behavior for ionic systems. Our results add an ionic compound to the very selective list of materials that can form monatomic wires and they contribute to the fundamental understanding of the mechanical properties of ceramic materials at the nanoscale.

Automated summary

Using in situ high-resolution transmission electron microscopy and density functional theory, this study reports the formation and rupture of ZrO2 atomic ionic wires. It is found that under tensile stress, the system favors the spontaneous formation of oxygen vacancies, which is a critical step in the formation of monatomic bridges. The vacancies exhibit ductilelike behavior at this length scale, which is unexpected for ionic systems.