Lattice Induced Short-Range Attraction between Like-Charged Colloidal Particles

We perform experiments and computer simulations to study the effective interactions between likecharged colloidal tracers moving in a two-dimensional fluctuating background of colloidal crystal. By a counting method that properly accounts for the configurational degeneracy of tracer pairs, we extract the relative probability of finding a tracer pair in neighboring triangular cells formed by background particles. We find that this probability at the nearest neighbor cell is remarkably greater than those at cells with larger separations, implying an effective attraction between the tracers. This effective attraction weakens sharply as the background lattice constant increases. Furthermore, we clarify that the lattice-mediated effective attraction originates from the minimization of free energy increase from deformation of the crystalline background due to the presence of diffusing tracers.

Automated summary

In this study, experiments and computer simulations were performed to investigate the effective interactions between like-charged colloidal tracers moving in a two-dimensional fluctuating background of colloidal crystal. The results show the presence of an effective attraction between the tracers, which weakens as the background lattice constant increases. This lattice-mediated attraction is a result of the minimization of free energy increase from deformation of the crystalline background due to the presence of diffusing tracers.