Journal
ORGANIC LETTERS
Volume 24, Issue 31, Pages 5674-5678Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c01990
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Funding
- NSFC [21801191, 21572163, 21873074]
- Wenzhou Science AMP
- Technology Bureau [2021G0027, G20210032]
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An iron(II)-catalyzed nitrene transfer reaction allows for the efficient synthesis of N-acyl sulfoximines with high functional-group compatibility. This catalytic transformation can be conducted under an air atmosphere at ambient temperature and can be scaled up to gram scale.
An iron(II)-catalyzed nitrene transfer reaction of sulfoxides with N-acyloxyamides has been developed, leading to the efficient construction of N-acyl sulfoximines with high functional-group compatibility. The current catalytic transformation was carried out under an air atmosphere at ambient temperature and could be scaled up to gram scale with a catalyst loading of 1 mol %. Application of the methodology was demonstrated by facile C-H acetoxylation and olefination using the N-acyl sulfoximine as the directing group.
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