Journal
ORGANIC LETTERS
Volume 24, Issue 32, Pages 6054-6059Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c02359
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Funding
- National Natural Science Foundation of China [21871240]
- State Key Laboratory of Elemento-organic Chemistry of Nankai University [202001]
- Fundamental Research Funds for the Central Universities [WK2060000017]
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A novel strategy of copper-catalyzed regio- and enantioselective hydrosilylation of 4-substituted vinylidenecyclo-hexanes with silanes was developed, which afforded the corresponding (cyclohexylidene)ethyl silanes in moderate to high yields with good enantioselectivities.
A novel strategy of copper-catalyzed regio-and enantioselective hydrosilylation of 4-substituted vinylidenecyclo-hexanes with silanes was developed. In this protocol, various allenes and silanes were used to afford the corresponding (cyclohexylidene)ethyl silanes in moderate to high yields with good enantioselectivities.
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