Journal
NATURE CHEMISTRY
Volume 14, Issue 8, Pages 846-848Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41557-022-01007-x
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In this study, a new strategy using N2O as the oxygen source under mild conditions was developed for the conversion of aryl halides to phenols.
Nitrous oxide is traditionally considered to be an inert molecule, and methods for its activation and utilization are currently limited. Now, a strategy has been developed - involving an organometallic Baeyer-Villiger step - for the conversion of aryl halides to phenols under mild conditions, using N2O as the oxygen source.
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