Journal
NANO RESEARCH
Volume 15, Issue 10, Pages 8865-8871Publisher
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-022-4673-z
Keywords
Fe doping; phosphide; heterostructure; all pH range; hydrogen evolution reaction (HER); electrolysis
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Funding
- National Natural Science Foundation of China [52172218]
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This study reports a novel biphosphide catalyst with improved hydrogen adsorption energy by constructing heterogeneous structures and cation doping. The obtained catalyst exhibits outstanding hydrogen evolution reaction performance at all pH range and shows low overpotential as an oxygen evolution reaction catalyst in alkaline solution. Additionally, it demonstrates low voltage and long durability for water electrolysis.
It is important to develop economical and durable electrocatalysts for sustainable energy conversion technology. However, the current catalysts still suffer from insufficient hydrogen adsorption energy. Herein, we report a kind of novel bi-phosphide catalyst through constructing heterogeneous structures and cation doping. The obtained sample delivers an outstanding hydrogen evolution reaction (HER) performance at all pH range. As oxygen evolution reaction (OER) electrocatalyst, Fe-CoP@Ni2P samples show an overpotential of 237 mV at 50 mA center dot cm(-2) in alkaline solution. For electrolysis of water, Fe-CoP@Ni2P catalysts deliver a cell voltage of 1.59 V at 50 mA center dot cm(-2) and long durability. Furthermore, density functional theory (DFT) calculation further confirms that the doped heterostructure promotes Gibbs free energy for hydrogen adsorption. And the significant increase in the density of total states (DOS) also enhances the catalytic activity of HER.
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