Journal
NANO RESEARCH
Volume 16, Issue 1, Pages 1726-1732Publisher
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-022-4772-x
Keywords
mesoporous hollow microspheres; carbon nanotubes; zinc-ion battery; ZnMn2O4
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Rechargeable zinc-ion batteries have gained attention as a future direction for large-scale energy storage due to their low cost, safety, environmental friendliness, and excellent electrochemical performance. In this study, hollow mesoporous ZnMn2O4/C microsphere cathode material with carbon nanotubes embedded in the shell was prepared for the first time using spray pyrolysis. The material showed high capacity retention and cycle stability, attributed to its hollow structure, excellent porosity, cationic defects, and the high electrical conductivity and strong adsorption of carbon nanotubes.
Recently, rechargeable zinc-ion batteries have been considered as the future development direction of large-scale energy storage due to their low price, safety, environmental friendliness, and excellent electrochemical performance. However, high-capacity, long-cycle stable cathode materials that can meet the demand are still to be developed. Herein, the hollow mesoporous ZnMn2O4/C microsphere cathode material with carbon nanotubes embedded in the shell was prepared by spray pyrolysis for the first time. Its capacity remained at 209.71 mAh.g(-1) after 150 cycles at a rate of 0.5 A.g(-1), and still maintained a specific capacity of 100.06 mAh.g(-1) at a rate of 1 kg(-1) after 1,000 cycles. The outstanding performance is attributed to the hollow structure that can effectively buffer large volume changes caused by ion intercalation and deintercalation, excellent porosity, cationic defects, and high electrical conductivity of carbon nanotubes and its strong adsorption to ZnMn2O4 nanoparticles.
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