4.8 Article

Synthesis of KVPO4F/Carbon Porous Single Crystalline Nanoplates for High-Rate Potassium-Ion Batteries

Journal

NANO LETTERS
Volume 22, Issue 12, Pages 4933-4940

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.2c01604

Keywords

fluorophosphate materials; interface engineering; nanostructure; cathode; potassium-ion batteries

Funding

  1. National Natural Science Foundation of China [22179063]

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In this study, carbon-coated KVPO4F nanoplates were synthesized using a simple one-step sintering process, where the V-F-C bond generated by fluorinated-polymer-derived carbon at the interface of KVPO4F/C nanoplates reduced F loss and improved the electronic conductivity and ion migration ability of KVPO4F. The as-synthesized KVPO4F/C cathode exhibited excellent capacity and rate capability, and the KVPO4F/C//soft carbon full cell showed a high energy density.
With high theoretical capacity and operating voltage, KVPO4F is a potential high energy density cathode material for potassium-ion batteries. However, its performance is usually limited by F loss, poor electronic conductivity, and unsteady electrode/electrolyte interface. Herein, a simple one-step sintering process is developed, where vanadium-oxalate-phosphite/phosphate frameworks and fluorinated polymer are used to synthesize carbon-coated KVPO4F nanoplates. It is found that the V-F-C bond generated by fluorinated-polymer-derived carbon at the interface of KVPO4F/C nanoplates diminishes the F loss, as well as enhances K-ions migration ability and the electronic conductivity of KVPO4F. The as-synthesized KVPO4F/C cathode delivers a reversible capacity of 106.5 mAh g(-1) at 0.2 C, a high working voltage of 4.28 V, and a rate capability with capacity of 73.8 mAh g(-1) at the ultrahigh current density of 100 C. In addition, a KVPO4F/C//soft carbon full cell exhibits a high energy density of 235.5 Wh kg(-1).

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