Journal
MOLECULAR DIVERSITY
Volume 26, Issue 6, Pages 3325-3336Publisher
SPRINGER
DOI: 10.1007/s11030-022-10393-w
Keywords
Chromene; Multi-component reaction; Indan-1,3-dione; 5,7-Dihydroxy-4-methylcoumarin; Magnetic nanoparticle; Recoverable catalyst
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Funding
- Yasouj University, Yasouj, Iran
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This research reports the synthesis of novel indeno[1,2-b]pyrano[2,3-f]chromene-2,12(13H)-dione derivatives in the presence of a newly introduced magnetically recoverable nanosolid acid catalyst. The prepared Fe3O4@SiO2-(CH2)(3)OPO3H2 nanocatalyst exhibited good catalytic activity for the synthesis of the derivatives. The nanocatalyst also showed great catalytic stability up to five consecutive runs.
In this research, the synthesis of novel indeno[1,2-b]pyrano[2,3-f]chromene-2,12(13H)-dione derivatives in the presence of a newly introduced magnetically recoverable nanosolid acid catalyst is reported. At the first, phosphoric acid-functionalized silica-coated Fe3O4 nanoparticles (Fe3O4@SiO2-(CH2)(3)OPO3H2) were prepared and well characterized using infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and energy-dispersive X-ray spectroscopy (EDS) techniques. Then, the catalytic activity of the prepared Fe3O4@ SiO2-(CH2)(3)OPO3H2 nanocatalyst was investigated for the synthesis of novel indeno[1,2-b]pyrano[2,3-f]chromene-2,12(13H)-dione derivatives via a one-pot and three-component condensation between 5,7-dihydroxy-4-methylcoumarin, indane-1, 3-dione, and various aromatic aldehydes under solvent-free condition. All the products are unknown, and their characterization was performed with the spectral data information obtained from their FT-IR, H-1 and (CNMR)-C-13, elemental analysis, and their melting points. The reusability study of the introduced nanosolid acid catalyst showed that the catalytic stability is almost completely remained up to five consecutive runs. [GRAPHICS] .
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