4.6 Article

Excellent fluorescence and photoelectricity of TiO2/Au/PS enabled by a synergistic carrier transfer effect

Journal

MATERIALS LETTERS
Volume 320, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2022.132344

Keywords

Semiconductors; Gold nanoparticles; Polymers; Fluorescence; Photocurrent

Funding

  1. National Natural Science Foundation of China [51273048, 21436004]

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In this study, a composite material of titanium dioxide (TiO2), gold nanoparticles (AuNPs), and polystyrene (PS) (TiO2/Au/PS) with excellent fluorescent and photoelectric properties was fabricated. The TiO2/Au/PS composite exhibited much stronger fluorescent emission compared to its single component counterparts and any pairwise combination. Furthermore, it also showed a stronger photogenerated current compared to TiO2/PS due to the synergistic enhancement effect.
Herein, the titanium dioxide (TiO2), gold nanoparticles (AuNPs), and polystyrene (PS) composite (TiO2/Au/PS) with excellent fluorescent and photoelectric properties was fabricated. TiO2 nanorods array was first synthesized on FTO, followed by deposition of AuNPs and coated with PS successively. The TiO2/Au/PS composites shows much stronger fluorescent emission than that of their single component counterparts and any pairwise combination. Further, TiO2/Au/PS exhibit much stronger photogenerated current compared to TiO2/PS. It can be attributed to the synergistic enhancement effect due to the carrier transfer among them. Those observations demonstrated that TiO2/Au/PS composites is a promising photoelectric devices material.

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