4.6 Article

Signature of adsorbed solvents for molecular electronics revealed via scanning tunneling microscopy

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 291, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2022.126645

Keywords

Molecular electronics; STM; Electronic transport; Organic solvents; Absorbed molecules; Break-junction

Funding

  1. Spanish Government [MAT2016-78625-C2, PID2019-109539 GB -C41]
  2. Generalitat Valenciana [PROMETEO/2017/139, ETEO/2021/017, CDEIGENT/2018/028]

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By using Scanning Tunneling Microscope (STM) and the Break Junction approach, this study reveals that organic solvents are not fully evaporated on gold substrates and characterizes their electronic transport properties in molecular electronics.
After evaporation of the organic solvents, benzene, toluene, and cyclohexane on gold substrates, Scanning Tunneling Microscope (STM) shows the presence of a remaining adsorbed layer. The different solvent molecules were individually observed at ambient conditions, and their electronic transport properties characterized through the STM in the Break Junction approach. The combination of both techniques reveals, on one hand, that solvents are not fully evaporated over the gold electrode and, secondly, characterize the electronic transport of the solvents in molecular electronics.

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