4.7 Article

Microstructural characteristics and mechanical properties of IC10 superalloy and (CoCrNi)94Al3Ti3 MEA joint brazed using NiCrSiB filler

Journal

MATERIALS CHARACTERIZATION
Volume 189, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2022.111964

Keywords

Microstructural characteristics; Mechanical properties; Ni3Al-based superalloy; Medium-entropy alloy; Brazing

Funding

  1. National Natural Science Foundations of China [51975480, 52075449, U1737205]

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This study focuses on the brazing of IC10 Ni3Al-based superalloy to (CoCrNi)(94)Al3Ti3 medium-entropy alloy (MEA) using NiCrSiB filler metal. The formation mechanism of the joint was investigated, and different regions such as diffusion-affected zone (DAZ), isothermal solidification zone (ISZ), and athermal solidification zone (ASZ) were observed. The presence of these zones influenced the mechanical properties and fracture behavior of the joint.
This study focuses on the brazing of IC10 Ni3Al-based superalloy to (CoCrNi)(94)Al3Ti3 medium-entropy alloy (MEA) using a NiCrSiB filler metal. The microstructure of the brazed joint was comprehensively investigated, and the forming mechanism of the joint was elucidated. The mechanical properties and fracture behavior of the joint were evaluated. The diffusion of boron from the filler to substrates led to the diffusion-affected zone (DAZ), and the M3B2- and M5B3-type boride were precipitated with the coherence of (3 1 0)(BCT)//(2 0 0)(FCC) (M3B2) and (0 0 2)(BCT)//(2 0 0)(FCC) (M5B3) adjacent to the IC10 and MEA substrate, namely the DAZ I and II respectively. In addition, the edge dislocation reduced the mismatch between the M3B2 boride and the gamma matrix. The isothermal solidification zone (ISZ) was formed near the DAZ when the liquidus temperature reached the brazing temperature due to the diffusion of boron and Si and the dissolution of substrates. The formation of ISZ was effectively activated at high brazing temperatures (1090, 1120, and 1150 degrees C). The athermal solidification zone (ASZ) was detected in the joint brazed at adopted temperatures, which mainly dominated by eutectic reactions and driven by cooling. The ASZ decreased shear strength of the defect-free joint, and readily accelerated initiation and propagation of cracks. The maximum shear strength of 554 MPa was obtained when the joint was brazed at 1120 degrees C for 10 min. The fracture mainly occurred in the ASZ (semi-cleavage), and passing through the DAZ (semi-cleavage) and ISZ (dimples).

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