4.6 Article

Carbon Nanotubes/Polydopamine/ZSM-5 Composite Soil Conditioner with Good Controlled Release and Adsorption Properties

Journal

LANGMUIR
Volume 38, Issue 32, Pages 9928-9939

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.2c01175

Keywords

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Funding

  1. projects of Capacity Building Project of Some Local Colleges and Universities in Shanghai [17030501200]
  2. National Natural Science Funds [51873103]
  3. Talent Program of Shanghai University of Engineering Science [2017RC422017]
  4. Scientific and Technological Support Projects in the Field of Biomedicine [19441901700]
  5. First-Rate Discipline Construction of Applied Chemistry [2018xk-B-06]

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This research developed a carbon nanotubes/polydopamine/ZSM-5 composite soil conditioner to address soil pollution. The composite conditioner exhibited superior sustained release and adsorption capabilities for fulvic acid and methylene blue compared to traditional materials. Additionally, it demonstrated the ability to promote plant growth.
Currently, the excessive application of fertilizers and the random discharge of waste water, waste gas, and residues have led to more and more serious soil pollution problems. Zeolite is the most promising material for preparing a green and environmentally friendly soil conditioner. Herein, the carbon nanotubes/polydopamine/ZSM-5 composite soil conditioner was prepared by a facile two-step method, and it was used to release fulvic acid and adsorb methylene blue to improve the environment. The cumulative release rate of the composite soil conditioner was 52% within 430 h for fulvic acid, which had a good sustained release effect and could be sustained-released in different acid-based surroundings. In addition, it showed a good adsorption capacity of methylene blue, and it is about 80.02 mg/g which was about six times higher than that of ZSM-5. It was beneficial for the adsorption of methylene blue in a neutral environment. Finally, it could promote the growth of brassica chinensis and maize, and the promotion effect was 60 and 35%, respectively. Therefore, the carbon nanotubes/polydopamine/ZSM-5 composite soil conditioner is a green and efficient material, which provides a new strategy to solve the problem of soil pollution. [GRAPHICS] .

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