4.7 Article

Ablation behaviors of SiC nanowire-reinforced ZrC-SiC coating-matrix integrated C/C composites with different ratios of precursors

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 42, Issue 15, Pages 6774-6784

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2022.07.043

Keywords

C; Ablation; Precursor infiltration pyrolysis; Coating-matrix integration

Funding

  1. Fundamental Science Center for Aviation and Gas Turbine Engines
  2. National Natural Science Foundations of China
  3. [P2021 -A-IV -002- 001]
  4. [51727804]
  5. [91860203]

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A novel method for preparing a coating on C/C composite is discussed in this study. By adding SiC nanowires, the method achieves the integration between the coating and the matrix, improving the adhesion of the coating. The results demonstrate that the material with a ZrC/SiC precursor ratio of 5:1 exhibits the highest resistance to ablation.
A novel method to prepare a coating on the C/C composite is discussed. The precursor infiltration pyrolysis method is usually applied to prepare interior ceramic matrix, thus SiC nanowires that can absorb the surficial precursor are added to prepare surficial ceramics. The method accomplishes the integration of the coating and the matrix so that no coating peels off after ablation. Moreover, the material with a ZrC/SiC precursor ratio of 5:1 (Z5S1), whose mass and linear rates are 0.47 mg/s and 0.95 mu m/s, exhibits the highest overall resistance to ablation. The results demonstrate that higher ZrC content and more uniform phase distribution are beneficial to keep ZrO2 in solid and form a denser and firmer oxide layer, which is more effective in improving the ablation resistance of the C/C composite.

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