4.7 Article

Enhanced sodium ion conduction of highly dense bulk zeolite X prepared by hydrothermal hot-pressing

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 42, Issue 8, Pages 3510-3514

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2022.02.050

Keywords

Zeolite; Cation conduction; Hydrothermal hot-pressing; Densification

Funding

  1. Japan Society for the Promo-tion of Science (JSPS) [19K22066]
  2. Grants-in-Aid for Scientific Research [19K22066] Funding Source: KAKEN

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Highly dense and translucent bulk zeolite X was fabricated successfully by hydrothermal hot-pressing method. Densification was achieved by the addition of a small amount of distilled water or a 1 mol/L NaOH solution, resulting in enhanced sodium ion conduction.
Highly dense bulk zeolite X with translucency was successfully fabricated by hydrothermal hot-pressing of zeolite powder at 150 degrees C. Densification was achieved by addition of a small amount of distilled water or a 1 mol/L NaOH solution. Enhanced sodium ion conduction was observed for the densified bulk ceramic bodies. The ion conductivities obtained were beyond 0.001 S/cm, and are comparable to those of practical solid electrolytes applied in electrochemical devices such as batteries and chemical sensors.

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