Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 144, Issue 34, Pages 15745-15753Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.2c06131
Keywords
-
Categories
Funding
- Spanish MINECO [RTI2018-095622-B-I00, 2017 SGR 238, EUR2020-112294]
- Catalan AGAUR [SEV-2017-0706]
- CERCA Program/Generalitat de Catalunya
- MCIN/AEI
- European Union NextGenerationEU/PRTR [CEX2019-000917-S]
- la Caixa Foundation [RTI2018-095622-B-I00, SEV-2017-0706]
- Ramon y Cajal fellowship [CEX2019-000917-S]
- [LCF/BQ/PR20/11770011]
- [100010434]
- [RYC2018-024328-I]
Ask authors/readers for more resources
In this study, a new approach based on using prefabricated cavities is proposed to design isoreticular multicomponent MOFs. By using prefabricated cavities and suitable linkers, three- and four-component MOFs can be constructed.
Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF. We demonstrate this concept with the formation of multicomponent HKUST-1 analogues, using a prefabricated cavity that comprises a cuboctahedral Rh(II) metal-organic polyhedron functionalized with 24 carboxylic acid groups. The cavities are reticulated in three dimensions via Cu(II)-paddlewheel clusters and (functionalized) 1,3,5-benzenetricarboxylate linkers to form three-and four -compo-nent HKUST-1 analogues.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available