Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 144, Issue 33, Pages 15038-15046Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.2c02937
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Funding
- NIGMS of the NIH
- NSF [1R35GM136360-01]
- [CHE 1625543]
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Researchers disclosed a ligand with an appended boron Lewis acid and successfully synthesized a series of tetrahedral complexes, including a boron-capped cuprous hydride, by metalation with Cu(I). Different reactivity modes were demonstrated depending on the chemical oxidation state, including hydride transfer to CO2 in the copper(I) state, oxidant-induced H2 evolution, and alkyne reduction.
We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of chemical oxidation: hydride transfer to CO2 in the copper(I) state and oxidant-induced H2 evolution as well as alkyne reduction.
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