Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 15, Pages 10208-10215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01175
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Funding
- National Natural Science Foundation of China [21901079, 21871100]
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Divergent synthetic methods were developed for transforming isatins to 2-cyanoaryl carbamate and 2-cyanoaryl urea derivatives, using ammonium carbamate as the nitrogen source and iodobenzene diacetate as the oxidant. This method features mild conditions, broad substrate scope, and the avoidance of toxic cyano-containing compounds.
Divergent synthetic methods for transforming isatins to 2-cyanoaryl carbamate and 2-cyanoaryl urea derivatives were developed using ammonium carbamate as the nitrogen source and iodobenzene diacetate as the oxidant. This reaction features mild conditions, broad substrate scope, and moreover, the use of toxic cyano-containing compounds is avoided.
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