Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 16, Pages 10555-10563Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01013
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- Oklahoma State University
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This Synopsis highlights recent developments in electron donor-acceptor (EDA) complex photochemistry, emphasizing the importance of catalysts in this synthetic strategy.
Electron donor-acceptor (EDA) complexes pro-vide a means to initiate radical reactions under visible light irradiation using substrates that do not absorb visible light individually. Catalytic approaches to complex formation are vital for advancing this synthetic strategy as it decouples the complexation and photogeneration of radicals from substrate functionalization, a limitation inherent to stoichiometric ap-proaches that restricts structural diversity. This Synopsis highlights recent developments in EDA complex photochemistry in which either the donor or acceptor are employed catalytically.
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