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Mercury removal using various modified V/Ti-based SCR catalysts: A review

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 436, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2022.129115

Keywords

Hg-0 Removal; Vanadium-Titanium-based catalysts; Doping modification; Gas composition resistance; Catalytic mechanism

Funding

  1. Joint Fund of the National Natural Science Foundation of China [U20A20302]
  2. Science Fund for Creative Research Groups of the Natural Science Foundation of Hebei Province, China - Science and Technology Project of Hebei Education Department [E2021202006, ZD2019065]
  3. Sci-ence and Technology Project of Hebei Education Department [ZD2019065]

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This article reviews many modification experiments on V/Ti catalysts, including studies on the performance and mercury removal mechanisms of these catalysts, aiming to guide future improvements.
Growing levels of mercury pollution has made countries urgently need a suitable mercury treatment technology. Among various technologies, heterogeneous oxidative mercury removal via different modified V/Ti-based SCR catalysts is considered as a promising approach due to excellent economic value and removal efficiency. Although various related modification experiments have been worked in recent years, the research on the performance, including activity and resistance, and mechanism of catalysts still needs to be improved, so it is necessary to summarize these experiments to guide further work. This article will review many modifications start from the V/Ti catalyst. Not only the performance of these catalysts, but also a lot of speculation about the mercury removal mechanism are include in our research. In addition, the characteristics of some modified catalysts have been linked with their oxidation mechanism and structural changes by comparing many studies, and finally attributed to some special properties of the corresponding modifiers. We expect this study will clarify the research progress of modified V/Ti-based SCR catalysts in mercury removal, and guide future modification so that some properties of the catalyst can be improved in a targeted manner.

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