Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 618, Issue -, Pages 283-289Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2022.03.048
Keywords
Attractive microgels; Viscoelasticity; Droplet coalescence; Dissipative particle dynamics; Maxwell model
Categories
Funding
- National Science Foundation [CMMI-1939362]
- U.S. DOE Office of Science Facility, at Brookhaven National Laboratory [DESC0012704]
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This study investigates the necking dynamics of attractive microgels and reveals that it exhibits liquid-like or solid-like behavior over different time and length scales. The growth of the neck is governed by stress relaxation of the polymers, and it shows an exponential decay in the rate of growth.
Hypothesis: Microgels can deform and interpenetrate and display colloid/polymer duality. The effective interaction of microgels in the collapsed state is governed by the interplay of polymer-solvent interfacial tension and bulk elasticity. A connecting neck is shown to mediate microgel interaction, but its temporal evolution has not been addressed. We hypothesize that the necking dynamics of attractive microgels exhibits liquid-like or solid-like behavior over different time and length scales.Experiments: We simulate the merging and pinching of attractive microgels with different crosslinking densities in explicit solvent using dissipative particle dynamics. The temporal coalescence dynamics of microgels is investigated and compared with simple liquid and polymeric droplets. We model the neck growth on long time scales using Maxwell model of polymer relaxation and compare the theoretical prediction with simulation data. The mechanical strength of the neck is characterized systematically via simulated pinch-off of microgels by steered molecular dynamics. Findings: We evidence a crossover in the coalescence dynamics reflecting the viscoelastic signature of microgels. In contrast to the common knowledge that viscoelastic materials respond elastically on short time scales, the early expansion of the microgel neck exhibits a linear behavior, similar to the viscous coalescence of liquid droplets. However, the late regime with arrested dynamics resembles sintering of solid particles. Through an analytical model relating microgel dynamics to neck growth, we show that the long-term behavior is governed by stress relaxation of the polymers in the neck region and predict an exponential decay in the rate of growth, which agrees favorably with the simulation. Different from coa-lescence, the thread thinning in microgel breakup primarily highlights its polymeric characteristics. (c) 2022 Elsevier Inc. All rights reserved.
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