Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 908, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.164599
Keywords
Li4Ti5O12@C; Sulfur-doped graphene; Lithium-ion batteries; Anode; High-rate capability
Categories
Funding
- Ministry of Education of China University Innovation Fund Project [2019YYA04001]
- Sub-project of Guangdong Provincial Science and Technology Planning Project (Foreign Science and Technology Cooperation Platform) [2019A050520001]
- Basic and Applied Basic Research Project of Guangzhou Science and Technology Bureau [202102080264]
- College Scientific Research Project of Guangzhou Education Bureau-Innovation Team Scientific Research Project [202032848]
- Provincial Higher Education Teaching Reform Project [2019-456]
- Guangzhou Education Science Planning Project [201911941]
- Provincial Quality Engineering Project [2019-89]
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A sulfur-doped graphene modified Li4Ti5O12@C nanocomposite (SG-T@C) was successfully fabricated via a sol-gel method assisted with solid-state route. The composite showed homogeneously dispersed Li4Ti5O12@C nanocrystals and the introduced sulfur-doped graphene acted as a conductive bridge, improving the electrical conductivity. The SG-T@C exhibited excellent high-rate performance and cycling stability, making it a promising electrode material for lithium-ion batteries.
Herein, sulfur-doped graphene modified Li4Ti5O12@C nanocomposite (SG-T@C) has been firstly fabricated via a sol-gel method assisted with solid-state route. In this composite, the Li4Ti5O12@C nanocrystals (T@C) are homogeneously dispersed into the two-dimensional sulfur-doped graphene. The introduced sulfur-doped graphene acted as conductive bridge within the resulted nanocomposite, thereby enhancing the electrical conductivity of T@C nanoparticles. The as-fabricated SG-T@C displays superior high-rate perfor-mance for lithium-ion batteries. It can deliver the capacities of 171.9 and 145.2 mAh/g at 0.1 and 10 degrees C respectively. Besides, SG-T@C exhibits 96.2% capacity retention at 20 degrees C over 800 cycles, demonstrating an excellent cycling stability. Therefore, the designed SG-T@C can be used as an advanced electrode for li-thium-ion batteries. (c) 2022 Elsevier B.V. All rights reserved.
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