Journal
IONICS
Volume 28, Issue 9, Pages 4185-4194Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-022-04655-8
Keywords
Lithium-ion battery; Anode material; Metal-organic frameworks; Fe2O3
Funding
- National Natural Science Foundation of China [21701083]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX20_3137]
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In this study, nitrogen-doped carbon-coated iron oxide material was prepared by a solvothermal method, which successfully addressed the issue of large volume change of iron oxide in lithium-ion batteries and improved its electronic conductivity and cycling stability.
Iron oxide (Fe2O3) has shown great potential to substitute carbon-based anode materials for lithium-ion batteries because of its high theoretical specific capacity. However, its huge volume change during the lithiation and de-lithiation processes has restricted its extensive application. Herein, we design a nitrogen-doped carbon-coated iron oxide (Fe2O3@NC) from Material of Institute Lavoisier (MIL)-53 (Fe) by a solvothermal method. Nitrogen-doped carbon can release the expansion stress of Fe2O3 to ensure the structural integrity and ameliorate electronic conductivity. Therefore, Fe2O3@NC displays a specific capacity of 875.4 mAh g(-1) at 100 mA g(-1) after 100 cycles and a good cycling stability of 342 mAh g(-1) at a high rate of 500 mA g(-1) in the best case.
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