The synergistic effect of equivalence ratio and initial temperature on laminar flame speed of syngas

The laminar flame speed of syngas (CO:H-2 = 1:1)/air premixed gas in a wide equivalence ratio range (0.6-5) and initial temperature (298-423 K) was studied by Bunsen burner. The results show that the laminar flame speed first increases and then decreases as the equivalence ratio increasing, which is a maximum laminar flame speed at n = 2. The laminar flame speed increases exponentially with the increase of initial temperature. For different equivalent ratios, the initial temperature effects on the laminar flame speed is different. The initial temperature effects for n = 2 (the most violent point of the reaction) is lower than others. It is found that H, O and OH are affected more and more when the equivalence ratio increase. When the equivalence ratio is far from 2, the reaction path changes, and the influence of initial temperature on syngas combustion also changes. The laminar flame speed of syngas is more severely affected by H + O-2 = O + OH and CO + OH = CO2 + H than others, which sensitivity coefficient is larger and change more greatly than others when the initial temperature and equivalence ratio change. Therefore, the laminar flame speed of syngas/air premixed gas is affected by the initial temperature and equivalence ratio. A new correlation is proposed to predict the laminar flame speed of syngas (CO:H-2 = 1:1)/air premixed gas under the synergistic effect of equivalence ratio and initial temperature (for equivalence ratios of 0.6-5, the initial temperature is 298-423 K). (C) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Automated summary

The laminar flame speed of syngas/air premixed gas is influenced by the initial temperature and equivalence ratio. The laminar flame speed increases exponentially with the increase of initial temperature and reaches a maximum at an equivalence ratio of 2. The effect of initial temperature on the laminar flame speed depends on the equivalence ratio. A new correlation is proposed to predict the laminar flame speed of syngas/air premixed gas considering the synergistic effect of equivalence ratio and initial temperature.