4.7 Article

Hydrogen detonation onset behind two obstructions with unequal blockage ratio and opening geometry

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 47, Issue 73, Pages 31468-31480

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.07.050

Keywords

Hydrogen detonation; Deflagration -to -detonation; transition; Detonation onset; Uneven obstacles; Perforate plate

Funding

  1. Mary Kay O'Connor Process Safety Center
  2. Artie McFerrin Department of Chemical Engineering at Texas A M University
  3. Turbomachinery Laboratory at Texas A M

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Experiments were conducted to investigate the detonation onset behind solid obstructions with uneven blockage ratio and opening shape. The study found that the geometric features of the second obstruction, including the opening shape, blockage ratio, and opening dimension, have varying effects on the detonation onset time and obstacle-induced shock strength. The critical conditions for detonation initiation were found to be correlated with the blockage ratio and effective opening dimension. The Taguchi analysis revealed that the blockage ratio of the second obstacle is the most influential factor for early detonation onset, while the shape and opening dimension have minor effects. This study emphasizes the importance of considering the blockage ratio pattern for overpressure estimation during gaseous explosions.
Experiments on detonation onset behind two solid obstructions with uneven blockage ratio (BR) and opening shape were carried out in premixed, stoichiometric, hydrogen-oxygen mixtures at 20 kPa. Three geometric features of the second obstruction (OB2) were investigated: the opening shape, BR, and minimum opening vertical dimension (d/l). Obstructions with blockage ratio increase across the obstacle pair (40%-80% and 40%-60%) presented shorter detonation onset time than obstacle pairs with unvaried BR (40%-40%). Modifications in the second obstacle geometry for pairs with 40%-40% and 40%-80% blockage had minimal effect on DDT time and obstacle-induced shock strength. Conversely, obstacle pairs with 40%-60% blockage experienced significant variation depending on the geometry employed. Critical conditions of detonation initiation immediately behind the second obstacle were found to correlate with BR and effective opening dimension (d(eff)/lambda); For OB2 with 60% and 80% BR, DDT limits correlate well with the upper and lower limits constrained by D-d(eff)/2l >= 1 and d(eff)/lambda >= 1, respectively. The Taguchi analysis showed that the second obstacle blockage is the factor that most influenced early deto-nation onset, both the shape and opening dimension had minor effects. This finding confirms the importance of BR pattern for overpressure estimation during gaseous explosions. (C) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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