Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 47, Issue 54, Pages 22972-22980Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.05.102
Keywords
Direct carbon fuel cells; Solid oxide fuel cell; Carbon fuel; Boudouard reaction; Fe catalyst
Categories
Funding
- Guangzhou Science and Technology Project [202102020685]
- Research Fund Program of Key Laboratory of Fuel Cell Technology of Guang- dong Province, Department of Education of Guangdong Prov- ince Project [2021KQNCX008]
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This paper reports a superior DC-SOFC powered by Fe-loaded used cigarette filter (UCF) biochar. The UCF biochar, characterized by its micron-sized structure and metal elements beneficial to the performance of DC-SOFC, serves as a feasible fuel with a peak power density of 341 mW cm-2.
As a typical waste, used cigarette filters (UCFs) are difficult to biodegrade and harmful to the environment. The direct carbon solid oxide fuel cell (DC-SOFC) is an energy conversion device that can utilize carbon directly, including biochar, as fuel. We report a superior DCSOFC powered by Fe-loaded UCF biochar in this paper. The microstructure and composition are characterized, indicating that the UCF biochar is micron-sized and contains metal elements such as K and Ca that are beneficial to the performance of DC-SOFC. The peak power density of the cell fueled by pure UCF biochar is 308 mW cm-2 and increases to 341 mW cm-2 after loading Fe as the catalyst, which is comparable to that of the cell with Fe-loaded activated carbon (368 mW cm-2). It proves the feasibility of the UCF biochar as fuel for DC-SOFCs, providing a theoretical basis and technical demonstration for the disposal and transformation of solid waste. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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