4.7 Article

Introducing N-Heterocyclic Iminophosphoranes (NHIPs): Synthesis by [3+2] Cycloaddition of Azophosphines with Alkynes and Reactivity Studies

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Organic Superbases in Recent Synthetic Methodology Research

Thomas R. Puleo et al.

Summary: The Concept article discusses recent applications of commercial organic superbases in modern synthetic methodologies, highlighting the advantages of organic superbases in discovering new base-catalyzed reactions, optimizing reactions that require stoichiometric Bronsted base, and in high-throughput experimentation technology.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Multidisciplinary

An Azophosphine Synthetic Equivalent of Mesitylphosphaazide and Its 1,3-Dipolar Cycloaddition Reactions

Martin-Louis Y. Riu et al.

Summary: A novel diazene compound was synthesized in this study, which underwent a series of reactions to form corresponding cycloadducts. Structural data of the cycloadducts were obtained, and the thermolysis process of this compound along with its kinetic parameters were investigated.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Chemistry, Multidisciplinary

Phosphorus-Containing Superbases: Recent Progress in the Chemistry of Electron-Abundant Phosphines and Phosphazenes

Robin F. Weitkamp et al.

Summary: The renaissance of Bronsted superbases is based on their ability to undergo various chemical transformations under mild conditions. Four major factors can be adjusted to tune their basicity selectively, including the nature of the basic center, electron donation by substituents, charge delocalization, and energy gain by hydrogen bonding. The appearance of neutral electron-rich phosphine and phosphazene bases in literature over the past decades has made them indispensable as auxiliary bases in deprotonation processes. Their applications in catalysis and coordination chemistry have also gained widespread interest.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Multidisciplinary

Easy wide scope access to luminescent fluorophosphoranes

Jaime Ponce-de-Leon et al.

Summary: The study reports an almost quantitative synthesis of homologous luminescent fluorophosphoranes using easily accessible reagents through SNAr cyclization. The DFT cyclization mechanism and alternative pathways to complete this isomerization are also studied and discussed.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Activating Pronucleophiles with High pKa Values: Chiral Organo-Superbases

Yu-Hui Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Inorganic & Nuclear

Cationic Copper Iminophosphorane Complexes as CuAAC Catalysts: A Mechanistic Study

Bas Venderbosch et al.

ORGANOMETALLICS (2020)

Article Chemistry, Inorganic & Nuclear

General Synthesis and Optical Properties of N-Aryl-N′-Silylcliazenes

Clement Chauvier et al.

ORGANOMETALLICS (2019)

Article Chemistry, Multidisciplinary

Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes

Yi-Chun Lin et al.

CHEMICAL SCIENCE (2018)

Review Chemistry, Multidisciplinary

Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

Mohand Melaimi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Quinone 1 e- and 2 e-/2 H+ Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships

Mioy T. Huynh et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Chiral IminophosphoranesAn Emerging Class of Superbase Organocatalysts

Henryk Krawczyk et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Review Chemistry, Multidisciplinary

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

Michele Soleilhavoup et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Article Chemistry, Multidisciplinary

Oxidative Addition at a Carbene Center: Synthesis of an Iminoboryl-CAAC Adduct

Fatme Dahcheh et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Chemistry, Multidisciplinary

Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes

Fatme Dahcheh et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Inorganic & Nuclear

Iminophosphorane-phosphines: Versatile ligands for homogeneous catalysis

Joaquin Garcia-Alvarez et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2014)

Article Chemistry, Multidisciplinary

Bifunctional Iminophosphorane Organocatalysts for Enantioselective Synthesis: Application to the Ketimine Nitro-Mannich Reaction

Marta G. Nunez et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Inorganic & Nuclear

Ag(I) and Au(I) complexes of sterically crowded cyclic phosphinimine ligands

Christopher C. Brown et al.

DALTON TRANSACTIONS (2010)

Review Chemistry, Multidisciplinary

Mitsunobu and Related Reactions: Advances and Applications

K. C. Kumara Swamy et al.

CHEMICAL REVIEWS (2009)

Article Chemistry, Multidisciplinary

Chiral tetraaminophosphonium salt-mediated asymmetric direct henry reaction

Daisuke Uraguchi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

Review Chemistry, Multidisciplinary

The Staudinger ligation - A gift to chemical biology'

M Kohn et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

Review Chemistry, Inorganic & Nuclear

From neutral iminophosphoranes to multianionic phosphazenates. The coordination chemistry of imino-aza-P(V) ligands

A Steiner et al.

COORDINATION CHEMISTRY REVIEWS (2002)

Article Chemistry, Organic

Synthesis of N-aryl-substituted iminophosphoranes and NMR spectroscopic investigation of their acid-base properties in acetonitrile

T Rodima et al.

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (2000)