Journal
INORGANIC CHEMISTRY
Volume 61, Issue 28, Pages 10624-10628Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c01478
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Funding
- National Natural Science Foundation of China [21731002, 21975104, 22150004, 22071141]
- Guangdong Major Project of Basic and Applied Research [2019B030302009]
- Guangdong Basic and Applied Basic Research Foundation [2019A1515012162]
- Open Fund of Guang- dong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications [2020A05]
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This is a study on a metallofullerene synthesized solvothermally with chlorobenzene as the solvent, which exhibits semiconductor properties.
Polymeric {Cu-6[(mu(3)-eta(2):eta(2):eta(2))(2)-C-60](FPz)(6)Clmiddot3C(6)H(5)Cl}(infinity) [FPz = 4-(trifluoromethyl)pyrazolate], synthesized solvothermally with chlorobenzene as the solvent, is a doubly-connecting trans bis-adduct hexanuclear cuprofullerene that has copper in mixed valence. The compound is an example of a metallofullerene having semiconductivity character.
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