4.7 Review

Characterization of naphthenic acids in crude oil samples-A literature review

Journal

FUEL
Volume 319, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2022.123775

Keywords

Naphthenic acids; Petroleum; Analytical techniques; Extraction; ARN tetrameric acids

Funding

  1. CENPES/PETROBRAS (Rio de Janeiro, Brazil) [2018/00110-4]
  2. Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [310057/2020-5]
  3. Graduate Program in Chemistry at the Federal University of Espirito Santo (UFES, Espirito Santo, Brazil)

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This article introduces the definition, formation mechanisms, and classification of naphthenic acids (NAs), as well as the challenges and phenomena related to the petrochemical industry. A bibliometric review shows an increase in the number of publications about NAs in recent years. The article also presents the primary extraction and characterization techniques of NAs, with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) being an excellent characterization method.
Given the ill-defined term naphthenic acids (NAs), we will classify NAs as the carboxylic acids found naturally in crude oil, which include both classic NAs (c-NAs, monoacids) and ox-NAs (polyacids). Resulting from the biodegradation mainly of saturated hydrocarbons, we briefly present the probable formation mechanisms of these acids. Throughout the text, we will revisit the classification of NAs by highlighting the challenges to the petrochemical industry in the processing of acidic petroleum, related phenomena, metal corrosion, and the formation of naphthenates, which can stabilize emulsions or even precipitate to obstruct surface installation systems. An exploratory bibliometric review highlights the expansion in the number of publications about NAs from the 2000s to present. Advances in chemical characterization analyses contributed to the discovery a specific group of high molecular weight tetrameric NAs, sometimes called ARN, that will receive special attention. Here, we present the primary extraction and characterization techniques used in the elucidation of NAs. We highlight characterization efforts by infrared spectrometry, nuclear magnetic resonance spectroscopy, liquid and gas chromatography, and mass spectrometry. Of note, Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) excels in the characterization of NAs and belongs to ultra-high resolution mass spectrometry (UHRMS) techniques, which redefined the analysis of the composition of crude oil and its fractions.

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