Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 461, Issue -, Pages 396-408Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2015.09.041
Keywords
Nanoparticles; Methylene blue; Adsorption; Oxidation; Catalysis; Nanosorbcats
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Nexen-CNOOC Ltd
- Alberta Innovates-Energy and Environment Solutions (AIEES) through the NSERC/NEXEN/AIEES Industrial Research Chair in Catalysis for Bitumen Upgrading
- Canadian Foundation for Innovation
- Alberta Science and Research Authority
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In this study methylene blue (MB) has been investigated for its adsorption and subsequent catalytic thermo-oxidative decomposition on surface of maghemite (gamma-Fe2O3) nanoparticles. The experimental adsorption isotherm fit well to the Freundlich model, indicating multi-sites adsorption. Computational modeling of the interaction between the MB molecule and gamma-Fe2O3 nanoparticle surface was carried out to get more insights into its adsorption behavior. Adsorption energies of MB molecules on the surface indicated that there are different adsorption sites on the surface of gamma-Fe2O3 confirming the findings regarding the adsorption isotherm. The catalytic activity of the gamma-Fe2O3 nanoparticles toward MB thermo-oxidative decomposition has been confirmed by subjecting the adsorbed MB to a thermo oxidation process up to 600 degrees C in a thermogravimetric analyzer. The experimental results showed a catalytic activity for post adsorption oxidation. The oxidation kinetics were studied using the Ozawa-Flyn-Wall (OFW) corrected method. The most probable mechanism functions were fifth and third orders for virgin MB and MB adsorbed onto gamma-Fe2O3 nanoparticles, respectively. Moreover, the results of thermodynamic transition state parameters, namely changes in Gibbs free energy of activation (Delta G(double dagger)), enthalpy of activation (Delta H-double dagger), and entropy of activation (Delta S-double dagger), emphasized the catalytic activity of gamma-Fe2O3 nanoparticles toward MB oxidation. (C) 2015 Elsevier Inc. All rights reserved.
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