4.7 Article

Novel visible-light-responsive Ag/AgCl@MIL-101 hybrid materials with synergistic photocatalytic activity

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 466, Issue -, Pages 284-290

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2015.12.045

Keywords

Visible light responsive photocatalyst; Ag/AgCl@MIL-101; Dye degradation

Funding

  1. National Natural Science Foundation of China [31171698, 31471643]
  2. Innovation Research Program of Department of Education of Hebei for Hebei Provincial Universities [LJRC009]
  3. Natural Science Foundation of Hebei Province [B2015204003]
  4. Natural Science Foundation of Agricultural University of Hebei [LG201404, ZD201506]

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In this paper, a novel visible-light responsive photocatalyst of Ag/AgCl@MIL-101 was synthesized via vapor diffusion-photoreduction strategy. The as-prepared composite material was characterized using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, ultraviolet-visible diffuse reflection spectra and X-ray photoelectron spectroscopy. Due to the synergistic effect between Ag/AgCl and MIL-101, the composite photocatalyst exhibited an enhanced and stable photoactivity for the degradation of Rhodamine B under visible light irradiation. The relationship between the photocatalytic activity and the structure of Ag/AgCl@MIL-101 hybrid material was discussed and the possible reaction mechanism was proposed. (C) 2015 Elsevier Inc. All rights reserved.

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