Journal
COMPOSITES SCIENCE AND TECHNOLOGY
Volume 225, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compscitech.2022.109484
Keywords
Multifunctional composites; Thermal properties; Anisotropy; Electro-spinning; MXene sheets
Categories
Funding
- National Natural Science Foundation of China [51972015, 52090034]
- Fundamental Research Funds for the Central Universities [XK1802-2]
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In this study, a soft fiber-stiff sheet synergistic strategy was demonstrated for fabricating superelastic and responsive anisotropic silica nanofiber/polyvinylpyrrolidone/MXene hybrid aerogels. The hybrid aerogel exhibits satisfactory thermal insulation performances at both high and low temperatures and shows high compressibility and fatigue resistance. This type of aerogel material holds great promise for applications in smart alarms, as well as heat and cold protection for electronic devices.
Although silica aerogels with ultralow thermal conductivity are competitive for thermal insulation, their deficiencies in mechanical properties and single function affect their wide applications. Herein, we demonstrate a soft fiber-stiff sheet synergistic strategy for fabricating superelastic and responsive anisotropic silica nanofiber/ polyvinylpyrrolidone/MXene hybrid aerogels by electrospinning, calcination, and directional-freezing. The anisotropic hybrid aerogel exhibits satisfactory thermal insulation performances at both high and low temperatures, delivering a low thermal conductivity of 21 mW m(-1) K-1. The top surface temperature of the hybrid aerogel maintains at similar to 74 degrees C after its standing on a hot plate of 300 degrees C. By putting the hybrid aerogel on a cold plate of-30 degrees C, its surface temperature is only 7.2 degrees C lower than the ambient temperature. Interestingly, the oxidation of MXene at high temperatures could transform the hybrid aerogel from electrically conductive to insulating, leading to sharp changes in electrical signals to trigger overheating alarm. Furthermore, the hybrid aerogel exhibits high compressibility and fatigue resistance with a high stress retention rate of 97.3% after 100 cycles under the compressive strain of 50%. Such compressive and thermally insulating aerogels are promising thermal management materials for smart alarms, and heat and cold protection of electronic devices.
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