The synergy of step-scheme heterojunction and sulfur vacancies in AgInS2/AgIn5S8 for highly efficient photocatalytic degradation of oxytetracycline

Constructing heterojunction and engineering intrinsic defect in the electronic structures of semiconductor photocatalysts have been recognized as useful strategies to meliorate their photocatalytic performance. Herein, AgInS2/AgIn5S8 step-scheme(S-scheme) heterojunction photocatalysts with abundant sulfur vacancies were obtained via one-step hydrothermal method by using L-cysteine as complexing agent. The optimal AgInS2/ AgIn5S8 exhibited a high removal efficiency of 90.5% in the photocatalytic degradation of oxytetracycline under visible light irradiation and could achieve a TOC removal rate of 61.0%. Moreover, the AgInS2/AgIn5S8 displayed a good long-term stability and reusability during consecutive application. The superior photocatalytic activity could be attributed to the rapid charge transfer under the driving force of internal electric field formed on the Sscheme heterojunction interface. The analysis results of degradation intermediates revealed that oxytetracycline was decomposed into small nontoxic molecules via deamination, dehydroxylation, decarbonylation and demethylation reactions by the attack of main active h+ and center dot O2- radicals. This study paves a new way to rationally design the novel AgInS2/AgIn5S8 step-scheme photocatalysts for antibiotic pollution remediation in water environment.

Automated summary

Constructing heterojunction and engineering intrinsic defect in semiconductor photocatalysts can effectively improve their photocatalytic performance. In this study, AgInS2/AgIn5S8 photocatalysts with abundant sulfur vacancies were synthesized via a one-step hydrothermal method. The optimized AgInS2/AgIn5S8 exhibited high removal efficiency and excellent long-term stability, attributed to its rapid charge transfer driven by the internal electric field of the heterojunction interface. This study provides a novel approach for the design of AgInS2/AgIn5S8 photocatalysts for antibiotic pollution remediation in water environments.