4.7 Article

Presence of metals and metalloids in crumb rubber used as infill of worldwide synthetic turf pitches: Exposure and risk assessment

Journal

CHEMOSPHERE
Volume 299, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2022.134379

Keywords

Crumb rubber; Elemental analysis; Inductively coupled plasma; Optical emission spectrometry; Heavy metals; Risk assessment

Funding

  1. Laboratory for Process Engineering, Environment, Biotechnology and Energy - LEPABE - FCT/MCTES (PIDDAC) [UIDB/00511/2020]
  2. FEDER [PTDC/EQU-EQU/28101/2017]
  3. national funds (PIDDAC) through FCT/MCTES
  4. FCT [2020.09041. BD, CEECINST/00049/2018]
  5. FCT - Fundacao para a Ciencia e a Tecnologia, I.P. [CEECIND/00676/2017]
  6. Fundação para a Ciência e a Tecnologia [PTDC/EQU-EQU/28101/2017, 2020.09041.BD] Funding Source: FCT

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Crumb rubber derived from end-of-life tires is commonly used as infill for synthetic turf pitches, but its use raises concerns about human health and environmental impact. A study found a wide range of metal concentrations in crumb rubber collected from artificial turf worldwide, with some metals exceeding safe limits. Ingestion of crumb rubber could pose non-carcinogenic and carcinogenic risks, particularly for younger individuals.
Crumb rubber derived from end-of-life tires (ELTs) is frequently used as infill of synthetic turf pitches, promoting circular economy. Although important to reduce the accumulation of waste, the use of recycled ELTs can be a problem to human health and the environment, both by direct contact during pitch use and by the release of these elements to the surroundings, mostly via volatilization and leaching. The present study aimed to evaluate the distribution of metals in ELT-derived crumb rubber collected in artificial turf worldwide and assess possible trends by country, pitch age and type (indoor vs. outdoor). The concentration ranges observed are very wide, especially in outdoor fields and for the most abundant metals, namely Zn (2989-5246 mg/kg), Fe (196-5194 mg/kg), Mg (188-1795 mg/kg) and Al (159-1882 mg/kg). For Zn, the levels were mostly above the safe limits set in European directives for relatable matrices (soils and toy materials), and the same happened for Pb, a much more toxic metal at lower concentrations. A multi-pathway human exposure study was also performed, and the risk assessment shows non-carcinogenic and carcinogenic risks from accidental crumb rubber ingestion (with Cr and Pb as major contributors) above the acceptable values for all the receptors except adult bystanders, with a higher significance to younger individuals. These results bring a different perspective regarding most of the studies reporting low risks related with exposure to metals in crumb rubber.

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