4.6 Article

Superior Electrocatalysis Delivered by a Directional Electron Transfer Cascade in Hierarchical CoNi/Ru@C

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 17, Issue 17, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202200449

Keywords

Ru-based alloying; directional electrocatalysis; cascade electron transfer; hydrogen production from seawater

Funding

  1. NSFC [51861135313]
  2. National 111 project [B20002]
  3. PCSIRT [IRT_15R52]
  4. Sino-German Centre's COVID-19 Related Bilateral Collaborative Project [C-0046]
  5. Guangdong Province International Scientific and Technological Cooperation Projects [2020A0505100036]
  6. Shenzhen Science and Technology Program [JCYJ20210324142010029]
  7. Guangdong Basic and Applied Basic Research Foundation [2022A1515010137, 2022A1515010504]
  8. Royal Society [UF150104]

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By utilizing a hierarchical confined material (CoNi/Ru@C), directional electron transfer was enabled, leading to superior hydrogen evolution in alkaline water/seawater.
Exploiting directional electron transfer cascades could lead to high-performance electrocatalysts for processes such as the hydrogen evolution reaction, but realising such systems is difficult. Herein, a hierarchical confined material (CoNi/Ru@C) is presented, which provides a suitable spatial junction to enable directional electron transfer, giving superior hydrogen evolution in alkaline water/seawater.

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