4.6 Article

N-Acenoacenes: Synthesis and Solid-State Properties

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 28, Issue 69, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202201916

Keywords

azaacenes; bisacenes; crystal engineering; semiconductors; solid-state packing

Funding

  1. DFG [SFB 1249]

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Four N-acenoacenes were synthesized and analyzed for their optoelectronic properties and solid-state packings. Two of the compounds showed good performance in organic thin-film transistors.
Four N-acenoacenes were synthesized and analyzed for their optoelectronic properties and solid-state packings. Two of the regioisomeric acridinoacridines are TIPS-ethynylated, whereas the other pair are Boc- and triflate substituted derivatives. The two TIPS-ethynyldiazaacenoacenes were processed into organic thin-film transistors with saturation hole mobilities reaching 2.9x10(-2) cm(2)(Vs)(-1).

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