☆ 4.6 Article

Progress in Convergent Paired Electrolysis

CHEMISTRY-A EUROPEAN JOURNAL (2022)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Radical-Radical Cross-Coupling Assisted N-S Bond Formation Using Alternating Current Protocol

Yong Yuan et al.

Summary: AC electrolysis is a promising protocol in organic synthesis that can achieve high atom-efficiency and avoid the use of external oxidants. This study successfully utilized AC electrolysis to achieve the unprecedented cross-coupling of aniline derivatives with thiophenols/thiols, resulting in the synthesis of numerous N-S bond-containing compounds.

CCS CHEMISTRY (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Recent Applications of Homogeneous Catalysis in Electrochemical Organic Synthesis

Xu Cheng et al.

Summary: This review presents recent advances in electrochemical homogeneous catalysis, with a focus on electrochemical noble-transition-metal catalysis, photoelectrochemical catalysis, and electrochemical enantioselective catalysis. The topics discussed include the mechanism of noble metal catalysts in the presence of cathodic hydrogen evolution, the enhancement of redox properties in photocatalysis, and the regulation of enantioselectivity in catalytic electrochemical reactions.

CCS CHEMISTRY (2022)

Add to Collection

Review Chemistry, Organic

Nickel-Catalyzed Paired Electrochemical Cross-Coupling of Aryl Halides with Nucleophiles

Yong Zhang et al.

Summary: Electrochemistry has gained attention as a versatile strategy in synthetic organic chemistry. Paired electrochemical reactions can improve atom economy and energy efficiency.

SYNTHESIS-STUTTGART (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis

Sheng Zhang et al.

Summary: The electrochemical arylation is an effective method for arylating alcohols, providing structurally diverse alcohols under mild conditions with good functional group tolerance and readily available starting materials. Research also suggests that there are two possible pathways involved in the alpha-arylation of benzylic alcohols.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Electrochemical C(sp3)-C(sp2) Cross-Coupling Reactions of Benzyl Trifluoroborate and Organic Halides**

Jian Luo et al.

Summary: This study reports a redox neutral electrochemical C(sp(2))-C(sp(3)) cross-coupling reaction conducted under ambient conditions using nonprecious metal catalysts. The reaction demonstrated good yields and a broad scope, with potential applications in pharmaceuticals and natural amino acid modification. The method, which proceeds through an unconventional radical transmetalation mechanism, is highly productive and expected to have widespread applications in organic synthesis.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Organic

Paired Electrolysis Enabled Ni-Catalyzed Unconventional Cascade Reductive Thiolation Using Sulfinates

Jun-Chen Kang et al.

Summary: This study reports a nickel-catalyzed cascade reductive thiolation of aryl halides with sulfinates driven by paired electrolysis, enabling the synthesis of various thioethers under mild conditions. Mechanistic exploration reveals that a cascade chemical step can occur at the electrode interface and potentially alter the reaction pathway in paired electrolysis, leading to the discovery of novel cascade reactions with unique reactivity.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Linear Paired Electrolysis-Realising 200 % Current Efficiency for Stoichiometric Transformations-The Electrochemical Bromination of Alkenes

Julia Strehl et al.

Summary: The generation of bromine through bromide oxidation and its subsequent use in bromination reactions during electrolysis achieved high current efficiencies of up to 200%. In addition, diiodination of cyclohexene and electrophilic aromatic bromination of electron-rich arenes were also achieved with current efficiencies of 168%.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Organic

Aminomethylation of Aryl Bromides by Nickel-Catalyzed Electrochemical Redox Neutral Cross Coupling

Yueyue Ma et al.

Summary: This method utilizes electrolysis processes, eliminating the need for a terminal oxidant, sacrificial anode, metal reductant, and prefunctionalized radical precursor. It shows broad functional group tolerance and provides a more environmentally friendly and synthetically practical approach for forming C(sp2)-C(sp3) bonds.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Electrochemical-Promoted Nickel-Catalyzed Oxidative Fluoroalkylation of Aryl Iodides

Zhenlei Zou et al.

Summary: This work presents a general strategy for metal-catalyzed cross-coupling of fluoroalkyl radicals with aryl halides under electrochemical conditions. By using paired electrolysis, the contradiction between anodic oxidation of fluoroalkyl sulfinates and cathodic reduction of low-valent nickel catalysts can be effectively addressed, thus allowing for direct introduction of fluorinated functionalities into aromatic systems.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides

Zijian Li et al.

Summary: This method utilizes alcohols and aryl bromides as coupling partners, combining anodic preparation and nickel catalysis to efficiently construct C(sp(2))-C(sp(3)) bonds. The nickel-catalyzed paired electrolysis reaction showcases a broad substrate scope suitable for the synthesis of multifunctional compounds.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Review Chemistry, Physical

Alternating current electrolysis for organic synthesis

Sachini Rodrigo et al.

Summary: Electrochemical organic synthesis using alternating current electrolysis has gained attention for its unique reactivity and environmentally friendly approach. This study aims to provide a brief overview of the history and recent advances in this field.

CURRENT OPINION IN ELECTROCHEMISTRY (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Reaching the Full Potential of Electroorganic Synthesis by Paired Electrolysis

Wenzhao Zhang et al.

Summary: Electroorganic synthesis is a rapidly developing research area within organic synthesis, focusing on paired electrolysis for simultaneous oxidation and reduction reactions to maximize atom and energy efficiency.

CHEMICAL RECORD (2021)

Add to Collection

Article Chemistry, Organic

One-Pot Synthesis of Tertiary Amides from Organic Trichlorides through Oxygen Atom Incorporation from Air by Convergent Paired Electrolysis

Zhongli Luo et al.

Summary: A convergent paired electrolysis catalyzed by a B12 complex has been developed for the one-pot synthesis of tertiary amides from organic trichlorides. Various readily available organic trichlorides can be converted to amides in the presence of tertiary amines through oxygen incorporation from air at room temperature. The amide formation mechanism in the paired electrolysis, mediated by a cobalt complex, was proposed.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Applied

From Bench to Plant: An Opportunity for Transition Metal Paired Electrocatalysis

Julien C. Vantourout

Summary: This article discusses the applications of electrochemistry and transition metal catalysis in medicinal and process chemistry, explores the difficulties in scaling up transition metal electrocatalysis from the lab to the industry, and argues that intrinsic characteristics related to different electrocatalytic modes are responsible for the absence of transition metal electrocatalysis in large-scale process chemistry.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Green Chemistry: Electrochemical Organic Transformations via Paired Electrolysis

Najoua Sbei et al.

Summary: Paired electrolysis is a highly efficient green process that reduces energy and time consumption, benefiting resource preservation and waste reduction. However, compatibility between oxidation and reduction processes is crucial for achieving optimal products.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Enantioconvergent Arylation of Racemic Secondary Alcohols to Chiral Tertiary Alcohols Enabled by Nickel/N-Heterocyclic Carbene Catalysis

Yuan Cai et al.

Summary: The study revealed a novel method for upgrading simple racemic secondary alcohols to enantioenriched tertiary alcohols, using an NHC-nickel catalyst to achieve efficient asymmetric alcohol alpha-C-H arylation, followed by asymmetric addition of arylboronic esters after dehydrogenation. Mechanistic studies and control experiments were conducted to understand the exceptional control over chemo- and enantioselectivity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Transition metal-catalyzed organic reactions in undivided electrochemical cells

Cong Ma et al.

Summary: Transition metal-catalyzed organic electrochemistry is a rapidly growing research area, with recent focus on transition metal-catalyzed paired electrolysis. Compared to conventional methods, this approach offers advantages in controlling reaction activity and selectivity and provides numerous opportunities for new and improved organic reaction methods in the future.

CHEMICAL SCIENCE (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Manganese-catalyzed chlorosulfonylation of terminal alkene and alkyne via convergent paired electrolysis

Mingming Yu et al.

Summary: This method utilizes manganese salt as a catalyst and redox mediator to achieve a successful radical addition reaction of terminal aryl alkenes and alkynes with sulfonyl chlorides in organic synthesis, producing highly selective products.

CELL REPORTS PHYSICAL SCIENCE (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Electrocatalysis as an enabling technology for organic synthesis

Luiz F. T. Novaes et al.

Summary: Electrochemistry has recently become a versatile strategy in achieving challenging transformations in synthetic organic chemistry. The use of redox-active electrocatalysts has increased in recent developments in electrosynthesis to enhance control over reactive intermediates. Electrocatalytic mediators allow for synthetic transformations to proceed in a manner different from purely chemical methods.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

The Persistent Radical Effect in Organic Synthesis

Dirk Leifert et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Electrochemistry

Basic Strategies and Types of Applications in Organic Electrochemistry

Gerhard Hilt

CHEMELECTROCHEM (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Site-Selective C-H Functionalization via Synergistic Use of Electrochemistry and Transition Metal Catalysis

Ke-Jin Jiao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

Add to Collection

Review Multidisciplinary Sciences

Designing for a green chemistry future

Julie B. Zimmerman et al.

SCIENCE (2020)

Add to Collection

Review Chemistry, Physical

Transition Metal-Catalyzed Organic Reactions under Visible Light: Recent Developments and Future Perspectives

Wan-Min Cheng et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C-H bonds

Lei Zhang et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Review Chemistry, Multidisciplinary

3d metallaelectrocatalysis for resource economical syntheses

Parthasarathy Gandeepan et al.

CHEMICAL SOCIETY REVIEWS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry

Dong Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Multidisciplinary Sciences

Visible light-induced direct α C-H functionalization of alcohols

Linbin Niu et al.

NATURE COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Physical

Electrochemically Promoted Nickel-Catalyzed Carbon-Sulfur Bond Formation

Yang Wang et al.

ACS CATALYSIS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

The Fundamentals Behind the Use of Flow Reactors in Electrochemistry

Timothy Noel et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical Oxidative Cross-Coupling with Hydrogen Evolution Reactions

Yong Yuan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Chemistry with Electrochemically Generated N-Centered Radicals

Peng Xiong et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Review Chemistry, Multidisciplinary

The Electrogenerated Cyanomethyl Anion: An Old Base Still Smart

Isabella Chiarotto et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Direct Arylation of α-Amino C(sp3)-H Bonds by Convergent Paired Electrolysis

Yueyue Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Iron-Catalyzed Remote Arylation of Aliphatic C-H Bond via 1,5-Hydrogen Shift

Bingwei Zhou et al.

ACS CATALYSIS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct alpha-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

Jack Twilton et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Using Physical Organic Chemistry To Shape the Course of Electrochemical Reactions

Kevin D. Moeller

CHEMICAL REVIEWS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical Arylation Reaction

Siegfried R. Waldvogel et al.

CHEMICAL REVIEWS (2018)

Add to Collection

Review Chemistry, Physical

Electrocatalytic C-H Activation

Nicolas Sauermann et al.

ACS CATALYSIS (2018)

Add to Collection

Article Chemistry, Physical

Complete electron economy by pairing electrolysis with hydrogenation

Rebecca S. Sherbo et al.

NATURE CATALYSIS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Electrogenerated Cationic Reactive Intermediates: The Pool Method and Further Advances

Jun-ichi Yoshida et al.

CHEMICAL REVIEWS (2018)

Add to Collection

Review Multidisciplinary Sciences

Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

Junwon Choi et al.

SCIENCE (2017)

Add to Collection

Article Chemistry, Physical

Engaging Radicals in Transition Metal-Catalyzed Cross-Coupling with Alkyl Electrophiles: Recent Advances

Atsushi Kaga et al.

ACS CATALYSIS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

The merger of transition metal and photocatalysis

Jack Twilton et al.

NATURE REVIEWS CHEMISTRY (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance

Ming Yan et al.

CHEMICAL REVIEWS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

The recent achievements of redox-neutral radical C-C cross-coupling enabled by visible-light

Jin Xie et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Transition metal-catalyzed cross-coupling reactions using organoindium reagents

Kai Zhao et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

One-world chemistry and systems thinking

Stephen A. Matlin et al.

NATURE CHEMISTRY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling

Mark D. Levin et al.

ACS CENTRAL SCIENCE (2016)

Add to Collection

Article Chemistry, Physical

Bimolecular Excited-State Electron Transfer with Surprisingly Long-Lived Radical Ions

Amani A. Alsam et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Redox catalysis in organic electrosynthesis: basic principles and recent developments

Robert Francke et al.

CHEMICAL SOCIETY REVIEWS (2014)

Add to Collection

Article Chemistry, Multidisciplinary

A General Strategy for Organocatalytic Activation of C-H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers

Katrine Qvortrup et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Organic

Electrochemical synthesis of amides: direct transformation of methyl ketones with formamides

Haolai Huang et al.

TETRAHEDRON LETTERS (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Deciding Whether To Go with the Flow: Evaluating the Merits of Flow Reactors for Synthesis

Ryan L. Hartman et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Review Chemistry, Multidisciplinary

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

Ranjan Jana et al.

CHEMICAL REVIEWS (2011)

Add to Collection

Review Chemistry, Multidisciplinary

Direct Sp(3) alpha-C-H activation and functionalization of alcohol and ether

Shu-Yu Zhang et al.

CHEMICAL SOCIETY REVIEWS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

An electrochemical tandem reaction: one-pot synthesis of homoallylic alcohols from alcohols in aqueous media

Li Zhang et al.

CHEMICAL COMMUNICATIONS (2010)

Add to Collection

Review Chemistry, Multidisciplinary

Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions

Alena Rudolph et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Convergent paired electrolysis for the three-component synthesis of protected homoallylic alcohols

G Hilt

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)

Add to Collection

Review Electrochemistry

A century of organic electrochemistry

H Lund

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2002)

Add to Collection

© Peeref 2019-2024. All rights reserved.