Progress in Convergent Paired Electrolysis

Convergent paired electrolysis combines both anodic and cathodic reactions simultaneously in an electrochemical transformation. It provides a highly energy-efficient and divergent approach to conventionally challenging and useful structures. However, the physical separation of the two half-electrode reactions makes it extremely difficult to couple the intermediates arising from the two electrodes. In this concept article, four strategies used in convergent paired electrolysis will be discussed from the perspective of the reaction mechanism: a) metal-catalyzed convergent paired electrolysis, b) convergent paired electrolysis enabled by persistent radical effects, c) microfluidic chemistry applied to convergent paired electrolysis, and d) alternating current electrolysis.

Automated summary

Convergent paired electrolysis combines anodic and cathodic reactions to provide an energy-efficient and versatile transformation method. However, the physical separation of the two half-electrode reactions makes coupling of the intermediates challenging. This concept article discusses four strategies used in convergent paired electrolysis from the perspective of reaction mechanism.