Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 28, Issue 47, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202201152
Keywords
convergent paired electrolysis; metal catalysis; microfluidic chemistry; persistent radicals
Categories
Funding
- National Science Foundation [CHE-1554906]
- National Natural Science Foundation of China [21702113]
- Anhui University [S020318006/069]
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Convergent paired electrolysis combines anodic and cathodic reactions to provide an energy-efficient and versatile transformation method. However, the physical separation of the two half-electrode reactions makes coupling of the intermediates challenging. This concept article discusses four strategies used in convergent paired electrolysis from the perspective of reaction mechanism.
Convergent paired electrolysis combines both anodic and cathodic reactions simultaneously in an electrochemical transformation. It provides a highly energy-efficient and divergent approach to conventionally challenging and useful structures. However, the physical separation of the two half-electrode reactions makes it extremely difficult to couple the intermediates arising from the two electrodes. In this concept article, four strategies used in convergent paired electrolysis will be discussed from the perspective of the reaction mechanism: a) metal-catalyzed convergent paired electrolysis, b) convergent paired electrolysis enabled by persistent radical effects, c) microfluidic chemistry applied to convergent paired electrolysis, and d) alternating current electrolysis.
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