4.3 Article

Nanostructural Analysis of SrTiO3:Al Photocatalyst Dispersed with Pt/Cr2O3/CoOOH Cocatalysts by Electron Microscopy

Journal

CHEMISTRY LETTERS
Volume 51, Issue 10, Pages 978-981

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.220329

Keywords

Photocatalyst; Electron microscopy; Cocatalyst

Funding

  1. University of Tokyo Advanced Characterization Nanotechnology Platform in the Nanotechnology Platform Project - Ministry o f Education, Culture, Sports, Science and Technology (MEXT), Japan [JPMXP09A-19-UT-0023]

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The distribution of cocatalysts on a water splitting photocatalyst was found to be selective, indicating anisotropic charge transport.
The distribution of cocatalysts on a water splitting photocatalyst was investigated using electron microscopy combined with energy dispersive X-ray spectroscopy. Pt, Cr, and Co cocatalyst components were dispersed on the surface of an Al-doped SrTiO3 photocatalyst by stepwise photodeposition. It was found that the Pt/Cr2O3 cocatalyst for hydrogen evolution and the CoOOH cocatalyst for oxygen evolution were selectively deposited on different crystal facets, indicating anisotropic charge transport.

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