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Proton-Coupled Reduction of the Catalytic [4Fe-4S] Cluster in [FeFe]-Hydrogenases
Moritz Senger et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
CODH-IV: A High-Efficiency CO-Scavenging CO Dehydrogenase with Resistance to O2
Lilith Domnik et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Nitrogenase Cofactor Assembly: An Elemental Inventory
Nathaniel S. Sickerman et al.
ACCOUNTS OF CHEMICAL RESEARCH (2017)
Applications of Photogating and Time Resolved Spectroscopy to Mechanistic Studies of Hydrogenases
Brandon L. Greene et al.
ACCOUNTS OF CHEMICAL RESEARCH (2017)
Models of the Ni-L and Ni-Sla States of the [NiFe]-Hydrogenase Active Site
Geoffrey M. Chambers et al.
INORGANIC CHEMISTRY (2016)
Genomic and metagenomic surveys of hydrogenase distribution indicate H2 is a widely utilised energy source for microbial growth and survival
Chris Greening et al.
ISME JOURNAL (2016)
Spectroscopic and Kinetic Properties of the Molybdenum-containing, NAD+ - dependent Formate Dehydrogenase from Ralstonia eutropha
Dimitri Niks et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2016)
Mechanism of hydrogen activation by [NiFe] hydrogenases
Rhiannon M. Evans et al.
NATURE CHEMICAL BIOLOGY (2016)
Guiding Principles of Hydrogenase Catalysis Instigated and Clarified by Protein Film Electrochemistry
Fraser A. Armstrong et al.
ACCOUNTS OF CHEMICAL RESEARCH (2016)
Why Nature Chose Selenium
Hans J. Reich et al.
ACS CHEMICAL BIOLOGY (2016)
Krypton Derivatization of an O2-Tolerant Membrane-Bound [NiFe] Hydrogenase Reveals a Hydrophobic Tunnel Network for Gas Transport
Jacqueline Kalms et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
[FeFe]-Hydrogenase with Chalcogenide Substitutions at the H-Cluster Maintains Full H2 Evolution Activity
Jens Noth et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)
Proton Inventory and Dynamics in the Nia-S to Nia-C Transition of a [NiFe] Hydrogenase
Brandon L. Greene et al.
BIOCHEMISTRY (2016)
The Molybdenum Active Site of Formate Dehydrogenase Is Capable of Catalyzing C-H Bond Cleavage and Oxygen Atom Transfer Reactions
Tobias Hartmann et al.
BIOCHEMISTRY (2016)
Oxygen Stability in the New [FeFe]-Hydrogenase from Clostridium beijerinckii SM10 (CbA5H)
Simone Morra et al.
BIOCHEMISTRY (2016)
Single-Amino Acid Modifications Reveal Additional Controls on the Proton Pathway of [FeFe]-Hydrogenase
Adam J. Comish et al.
BIOCHEMISTRY (2016)
Chemical assembly of multiple metal cofactors: The heterologously expressed multidomain [FeFe]-hydrogenase from Megasphaera elsdenii
Giorgio Caserta et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2016)
The effect of a C298D mutation in CaHydA [FeFe]-hydrogenase: Insights into the protein-metal cluster interaction by EPR and FTIR spectroscopic investigation
Simone Morra et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2016)
Reactivation from the Ni-B state in [NiFe] hydrogenase of Ralstonia eutropha is controlled by reduction of the superoxidised proximal cluster
Valentin Radu et al.
CHEMICAL COMMUNICATIONS (2016)
Structure and function of [NiFe] hydrogenases
Hideaki Ogata et al.
JOURNAL OF BIOCHEMISTRY (2016)
Protonation states of intermediates in the reaction mechanism of [NiFe] hydrogenase studied by computational methods
Geng Dong et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2016)
Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides
Olbelina A. Ulloa et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Glutamate Gated Proton-Coupled Electron Transfer Activity of a [NiFe]-Hydrogenase
Brandon L. Greene et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)
Carbon-sulfur bond-forming reaction catalysed by the radical SAM enzyme HydE
Roman Rohac et al.
NATURE CHEMISTRY (2016)
Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase
Deborah Brazzolotto et al.
NATURE CHEMISTRY (2016)
Photoactivation of the Ni-SIr state to the Ni-SIa state in [NiFe] hydrogenase: FT-IR study on the light reactivity of the ready Ni-SIr state and as-isolated enzyme revisited
Hulin Tai et al.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)
Assembly scaffold NifEN: A structural and functional homolog of the nitrogenase catalytic component
Aaron W. Fay et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2016)
Stepwise isotope editing of [FeFe]-hydrogenases exposes cofactor dynamics
Moritz Senger et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2016)
The methanogenic CO2 reducing-and-fixing enzyme is bifunctional and contains 46 [4Fe-4S] clusters
Tristan Wagner et al.
SCIENCE (2016)
Structure of an Actinobacterial-Type [NiFe]-Hydrogenase Reveals Insight into O2-Tolerant H2 Oxidation
Caspar Schaefer et al.
STRUCTURE (2016)
Vibrational spectroscopy reveals the initial steps of biological hydrogen evolution
S. Katz et al.
CHEMICAL SCIENCE (2016)
A structural view of synthetic cofactor integration into [FeFe]-hydrogenases
J. Esselborn et al.
CHEMICAL SCIENCE (2016)
Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation
Bharathi Konkena et al.
NATURE COMMUNICATIONS (2016)
Nitrogenase FeMoco investigated by spatially resolved anomalous dispersion refinement
Thomas Spatzal et al.
NATURE COMMUNICATIONS (2016)
HydDB: A web tool for hydrogenase classification and analysis
Dan Sondergaard et al.
SCIENTIFIC REPORTS (2016)
From Enzyme Maturation to Synthetic Chemistry: The Case of Hydrogenases
Vincent Artero et al.
ACCOUNTS OF CHEMICAL RESEARCH (2015)
Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H2 Oxidation by a NiFe Hydrogenase
Ricardo Hidalgo et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
Impact of the Iron-Sulfur Cluster Proximal to the Active Site on the Catalytic Function of an O2-Tolerant NAD+-Reducing [NiFe]-Hydrogenase
Katja Karstens et al.
BIOCHEMISTRY (2015)
Hybrid [FeFe]-Hydrogenases with Modified Active Sites Show Remarkable Residual Enzymatic Activity
Judith F. Siebel et al.
BIOCHEMISTRY (2015)
[FeFe]-Hydrogenase Maturation: Insights into the Role HydE Plays in Dithiomethylamine Biosynthesis
Jeremiah N. Betz et al.
BIOCHEMISTRY (2015)
The Carbon Monoxide Dehydrogenase from Desulfovibrio vulgaris
Jessica Hadj-Said et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2015)
Assembly and catalysis of molybdenum or tungsten-containing formate dehydrogenases from bacteria
Tobias Hartmann et al.
BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS (2015)
Oxidative inactivation of NiFeSe hydrogenase
Pierre Ceccaldi et al.
CHEMICAL COMMUNICATIONS (2015)
O2 Inhibition of Ni-Containing CO Dehydrogenase Is Partly Reversible
Meriem Merrouch et al.
CHEMISTRY-A EUROPEAN JOURNAL (2015)
The pathway for serial proton supply to the active site of nitrogenase: enhanced density functional modeling of the Grotthuss mechanism
Ian Dance
DALTON TRANSACTIONS (2015)
'Sulfido and Cysteine Ligation Changes at the Molybdenum Cofactor during Substrate Conversion by Formate Dehydrogenase (FDH) from Rhodobacter capsulatus
Peer Schrapers et al.
INORGANIC CHEMISTRY (2015)
Designed Surface Residue Substitutions in [NiFe] Hydrogenase that Improve Electron Transfer Characteristics
Isaac T. Yonemoto et al.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2015)
A Threonine Stabilizes the NiC and NiR Catalytic Intermediates of [NiFe]-hydrogenase
Abbas Abou-Hamdan et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2015)
FT-IR Characterization of the Light-Induced Ni-L2 and Ni-L3 States of [NiFe] Hydrogenase from Desulfovibrio vulgaris Miyazaki F
Hulin Tai et al.
JOURNAL OF PHYSICAL CHEMISTRY B (2015)
Electrochemical Measurements of the Kinetics of Inhibition of Two FeFe Hydrogenases by O2 Demonstrate That the Reaction Is Partly Reversible
Christophe Orain et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
[FeFe]-Hydrogenase Oxygen Inactivation Is Initiated at the H Cluster 2Fe Subcluster
Kevin D. Swanson et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Discovery of Dark pH-Dependent H+ Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate
Bonnie J. Murphy et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Proton-Coupled Electron Transfer Dynamics in the Catalytic Mechanism of a [NiFe]-Hydrogenase
Brandon L. Greene et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Spectroscopic Characterization of the Bridging Amine in the Active Site of [FeFe] Hydrogenase Using lsotopologues of the H-Cluster
Agnieszka Adamska-Venkatesh et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Proton-Coupled Electron Transfer: Moving Together and Charging Forward
Sharon Hammes-Schiffer
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase
Hideaki Ogata et al.
NATURE (2015)
Structural differences between the active sites of the Ni-A and Ni-B states of the [NiFe] hydrogenase: an approach by quantum chemistry and single crystal ENDOR spectroscopy
Jessica L. Barilone et al.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)
Artificially maturated [FeFe] hydrogenase from Chlamydomonas reinhardtii: a HYSCORE and ENDOR study of a non-natural H-cluster
Agnieszka Adamska-Venkatesh et al.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)
Uncoupling binding of substrate CO from turnover by vanadium nitrogenase
Chi Chung Lee et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2015)
What is the trigger mechanism for the reversal of electron flow in oxygen-tolerant [NiFe] hydrogenases?
Ian Dance
CHEMICAL SCIENCE (2015)
Refining the pathway of carbide insertion into the nitrogenase M-cluster
Jared A. Wiig et al.
NATURE COMMUNICATIONS (2015)
Sulphur shuttling across a chaperone during molybdenum cofactor maturation
Pascal Arnoux et al.
NATURE COMMUNICATIONS (2015)
Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy
Hideaki Ogata et al.
NATURE COMMUNICATIONS (2015)
Catalysis-dependent selenium incorporation and migration in the nitrogenase active site iron-molybdenum cofactor
Thomas Spatzal et al.
ELIFE (2015)
A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel-iron-hydride in [NiFe] hydrogenase
Hongxin Wang et al.
JOURNAL OF SYNCHROTRON RADIATION (2015)
Crystal Structure of HydG from Carboxydothermus hydrogenoformans: A Trifunctional [FeFe]-Hydrogenase Maturase
Yvain Nicolet et al.
CHEMBIOCHEM (2015)
Molybdenum and tungsten-dependent formate dehydrogenases
Luisa B. Maia et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2015)
The aerobic CO dehydrogenase from Oligotropha carboxidovorans
Russ Hille et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2015)
Structural Evidence for Asymmetrical Nucleotide Interactions in Nitrogenase
F. Akif Tezcan et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation
Bojana Ginovska-Pangovska et al.
ACCOUNTS OF CHEMICAL RESEARCH (2014)
Differential Reduction of CO2 by Molybdenum and Vanadium Nitrogenases
Johannes G. Rebelein et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Control of the Transition between Ni-C and Ni-SIa States by the Redox State of the Proximal Fe-S Cluster in the Catalytic Cycle of [NiFe] Hydrogenase
Hulin Tai et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Aerobic Damage to [FeFe]-Hydrogenases: Activation Barriers for the Chemical Attachment of O2
Adam Kubas et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
How the structure of the large subunit controls function in an oxygen-tolerant [NiFe]-hydrogenase
Lisa Bowman et al.
BIOCHEMICAL JOURNAL (2014)
Nonenzymatic Synthesis of the P-Cluster in the Nitrogenase MoFe Protein: Evidence of the Involvement of All-Ferrous [Fe4S4]0 Intermediates
Kresimir Rupnik et al.
BIOCHEMISTRY (2014)
Another Role for CO with Nitrogenase? CO Stimulates Hydrogen Evolution Catalyzed by Variant Azotobacter vinelandii Mo-Nitrogenases
Karl Fisher et al.
BIOCHEMISTRY (2014)
Molecular dynamics study of the proposed proton transport pathways in [FeFe]-hydrogenase
Bojana Ginovska-Pangovska et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2014)
A broad survey reveals substitution tolerance of residues ligating FeS clusters in [NiFe] hydrogenase
Isaac T. Yonemoto et al.
BMC BIOCHEMISTRY (2014)
Biosynthesis of Nitrogenase Metalloclusters
Markus W. Ribbe et al.
CHEMICAL REVIEWS (2014)
Introduction: Bioinorganic Enzymology II
Richard H. Holm et al.
CHEMICAL REVIEWS (2014)
The Mononuclear Molybdenum Enzymes
Russ Hille et al.
CHEMICAL REVIEWS (2014)
Metalloproteins Containing Cytochrome, Iron-Sulfur, or Copper Redox Centers
Jing Liu et al.
CHEMICAL REVIEWS (2014)
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
Brian M. Hoffman et al.
CHEMICAL REVIEWS (2014)
Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase
Mehmet Can et al.
CHEMICAL REVIEWS (2014)
Mimicking hydrogenases: From biomimetics to artificial enzymes
Trevor R. Simmons et al.
COORDINATION CHEMISTRY REVIEWS (2014)
FeFe hydrogenase reductive inactivation and implication for catalysis
Viviane Hajj et al.
ENERGY & ENVIRONMENTAL SCIENCE (2014)
The chaperone FdsC for Rhodobacter capsulatus formate dehydrogenase binds the bis-molybdopterin guanine dinucleotide cofactor
Nadine Boehmer et al.
FEBS LETTERS (2014)
Experimental evidence of an acetate transporter protein and characterization of acetate activation in aceticlastic methanogenesis of Methanosarcina mazei
Cornelia Welte et al.
FEMS MICROBIOLOGY LETTERS (2014)
Activation Barriers of Oxygen Transformation at the Active Site of [FeFe] Hydrogenases
Arndt R. Finkelmann et al.
INORGANIC CHEMISTRY (2014)
Engineering Hydrogen Gas Production from Formate in a Hyperthermophile by Heterologous Production of an 18-Subunit Membrane-bound Complex
Gina L. Lipscomb et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2014)
Electron transfer activation of a second water channel for proton transport in [FeFe]-hydrogenase
Olaseni Sode et al.
JOURNAL OF CHEMICAL PHYSICS (2014)
The F420-Reducing [NiFe]-Hydrogenase Complex from Methanothermobacter marburgensis, the First X-ray Structure of a Group 3 Family Member
Stella Vitt et al.
JOURNAL OF MOLECULAR BIOLOGY (2014)
Multiscale Simulations Give Insight into the Hydrogen In and Out Pathways of [NiFe]-Hydrogenases from Aquifex aeolicus and Desulfovibrio fructosovorans
Francesco Oteri et al.
JOURNAL OF PHYSICAL CHEMISTRY B (2014)
Proton Transport in Clostridium pasteurianum [FeFe] Hydrogenase I: A Computational Study
Hai Long et al.
JOURNAL OF PHYSICAL CHEMISTRY B (2014)
Resonance Raman Spectroscopy on [NiFe] Hydrogenase Provides Structural Insights into Catalytic Intermediates and Reactions
Marius Horch et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Disclosure of Key Stereoelectronic Factors for Efficient H2 Binding and Cleavage in the Active Site of [NiFe]-Hydrogenases
Maurizio Bruschi et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
New Redox States Observed in [FeFe] Hydrogenases Reveal Redox Coupling Within the H-Cluster
Agnieszka Adamska-Venkatesh et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Investigations on the Role of Proton-Coupled Electron Transfer in Hydrogen Activation by [FeFe]-Hydrogenase
David W. Mulder et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Reversible [4Fe-3S] cluster morphing in an O2-tolerant [NiFe] hydrogenase
Stefan Frielingsdorf et al.
NATURE CHEMICAL BIOLOGY (2014)
A redox hydrogel protects hydrogenase from high-potential deactivation and oxygen damage
Nicolas Plumere et al.
NATURE CHEMISTRY (2014)
The HydG Enzyme Generates an Fe(CO)2(CN) Synthon in Assembly of the FeFe Hydrogenase H-Cluster
Jon M. Kuchenreuther et al.
SCIENCE (2014)
Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase
Thomas Spatzal et al.
SCIENCE (2014)
Identification of a spin-coupled Mo(III) in the nitrogenase iron-molybdenum cofactor
Ragnar Bjornsson et al.
CHEMICAL SCIENCE (2014)
Nitrogenase: A Draft Mechanism
Brian M. Hoffman et al.
ACCOUNTS OF CHEMICAL RESEARCH (2013)
Observation of the Fe-CN and Fe-CO Vibrations in the Active Site of [NiFe] Hydrogenase by Nuclear Resonance Vibrational Spectroscopy
Saeed Kamali et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Resonance Raman Spectroscopy as a Tool to Monitor the Active Site of Hydrogenases
Elisabeth Siebert et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
The Structural Plasticity of the Proximal [4Fe3S] Cluster is Responsible for the O2 Tolerance of Membrane-Bound [NiFe] Hydrogenases
Jean-Marie Mouesca et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Photosystem II: The Reaction Center of Oxygenic Photosynthesis
David J. Vinyard et al.
ANNUAL REVIEW OF BIOCHEMISTRY, VOL 82 (2013)
Cysteine 295 indirectly affects Ni coordination of carbon monoxide dehydrogenase-II C-cluster
Takahiro Inoue et al.
BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS (2013)
On the antiquity of metalloenzymes and their substrates in bioenergetics
Wolfgang Nitschke et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2013)
[NiFe] hydrogenases: A common active site for hydrogen metabolism under diverse conditions
Hannah S. Shafaat et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2013)
Nitrogenase reduction of carbon-containing compounds
Lance C. Seefeldt et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2013)
Molecular basis of [FeFe]-hydrogenase function
Martin Winkler et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2013)
Molybdenum enzymes, their maturation and molybdenum cofactor biosynthesis in Escherichia coli
Chantal Iobbi-Nivol et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2013)
Structural foundations for the O2 resistance of Desulfomicrobium baculatum [NiFeSe]-hydrogenase
Anne Volbeda et al.
CHEMICAL COMMUNICATIONS (2013)
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation
Aaron M. Appel et al.
CHEMICAL REVIEWS (2013)
Developing more sustainable processes for ammonia synthesis
Yoshiaki Tanabe et al.
COORDINATION CHEMISTRY REVIEWS (2013)
The oxygen-tolerant and NAD+-dependent formate dehydrogenase from Rhodobacter capsulatus is able to catalyze the reduction of CO2 to formate
Tobias Hartmann et al.
FEBS JOURNAL (2013)
Arginine171 of Chlamydomonas reinhardtii [Fe-Fe] hydrogenase HydA1 plays a crucial role in electron transfer to its catalytic center
Kateryna Sybirna et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)
Redox state-dependent changes in the crystal structure of [NiFeSe] hydrogenase from Desulfovibrio vulgaris Hildenborough
Marta C. Marques et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)
Principles of Sustained Enzymatic Hydrogen Oxidation in the Presence of Oxygen - The Crucial Influence of High Potential Fe-S Clusters in the Electron Relay of [NiFe]-Hydrogenases
Rhiannon M. Evans et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
A Metal-Metal Bond in the Light-Induced State of [NiFe] Hydrogenases with Relevance to Hydrogen Evolution
Mario Kampa et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Uncovering a Dynamically Formed Substrate Access Tunnel in Carbon Monoxide Dehydrogenase/Acetyl-CoA Synthase
Po-hung Wang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Catalytic Production of Hydrogen Peroxide and Water by Oxygen-Tolerant [NiFe]-Hydrogenase during H2 Cycling in the Presence of O2
Lars Lauterbach et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Hydrogen Activation by Biomimetic [NiFe]-Hydrogenase Model Containing Protected Cyanide Cofactors
Brian C. Manor et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Biomimetic assembly and activation of [FeFe]-hydrogenases
G. Berggren et al.
NATURE (2013)
ENZYMEs Nailing down hydrogenase
Michael J. Maroney
NATURE CHEMICAL BIOLOGY (2013)
Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic
Julian Esselborn et al.
NATURE CHEMICAL BIOLOGY (2013)
Structure, function and biosynthesis of O2-tolerant hydrogenases
Johannes Fritsch et al.
NATURE REVIEWS MICROBIOLOGY (2013)
Early bioenergetic evolution
Filipa L. Sousa et al.
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES (2013)
The inevitable journey to being
Michael J. Russell et al.
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES (2013)
Studies on hydrogenase
Tatsuhiko Yagi et al.
PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES (2013)
Electronic structure of the unique [4Fe-3S] cluster in O2-tolerant hydrogenases characterized by 57Fe Mossbauer and EPR spectroscopy
Maria-Eirini Pandelia et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2013)
Reply to Mouesca et al.: Electronic structure of the proximal [4Fe-3S] cluster of O2-tolerant [NiFe] hydrogenases
Maria-Eirini Pandelia et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2013)
Electronic states of the O2-tolerant [NiFe] hydrogenase proximal cluster
Jean-Marie Mouesca et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2013)
On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase
Zhi-Yong Yang et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2013)
A Functional [NiFe]Hydrogenase Mimic That Catalyzes Electron and Hydride Transfer from H2
Seiji Ogo et al.
SCIENCE (2013)
Direct and Reversible Hydrogenation of CO2 to Formate by a Bacterial Carbon Dioxide Reductase
K. Schuchmann et al.
SCIENCE (2013)
Crystal Structure of the O2-Tolerant Membrane-Bound Hydrogenase 1 from Escherichia coli in Complex with Its Cognate Cytochrome b
Anne Volbeda et al.
STRUCTURE (2013)
De novo modeling of the F420-reducing [NiFe]-hydrogenase from a methanogenic archaeon by cryo-electron microscopy
Deryck J. Mills et al.
ELIFE (2013)
Dual organism design cycle reveals small subunit substitutions that improve [NiFe] hydrogenase hydrogen evolution
Isaac T. Yonemoto et al.
JOURNAL OF BIOLOGICAL ENGINEERING (2013)
Identification and Characterization of the Super-Reduced State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?
Agnieszka Adamska et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
The hows and whys of aerobic H2 metabolism
Alison Parkin et al.
CURRENT OPINION IN CHEMICAL BIOLOGY (2012)
Evidence for the Formation of a Mo-H Intermediate in the Catalytic Cycle of Formate Dehydrogenase
Matteo Tiberti et al.
INORGANIC CHEMISTRY (2012)
Evolution of an [FeFe] hydrogenase with decreased oxygen sensitivity
Alyssa S. Bingham et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2012)
Importance of the Protein Framework for Catalytic Activity of [FeFe]-Hydrogenases
Philipp Knoerzer et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2012)
A Sulfurtransferase Is Essential for Activity of Formate Dehydrogenases in Escherichia coli
Remi Thome et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2012)
P+ State of Nitrogenase P-Cluster Exhibits Electronic Structure of a [Fe4S4]+ Cluster
Kresimir Rupnik et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
EPR Spectroscopic Studies of the Fe-S Clusters in the O2-Tolerant [NiFe]-Hydrogenase Hyd-1 from Escherichia coli and Characterization of the Unique [4Fe-3S] Cluster by HYSCORE
Maxie M. Roessler et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Understanding and Tuning the Catalytic Bias of Hydrogenase
Abbas Abou Hamdan et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Site Saturation Mutagenesis Demonstrates a Central Role for Cysteine 298 as Proton Donor to the Catalytic Site in CaHydA [FeFe]-Hydrogenase
Simone Morra et al.
PLOS ONE (2012)
X-ray crystallographic and computational studies of the O2-tolerant [NiFe]-hydrogenase 1 from Escherichia coli
Anne Volbeda et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)
Relation between anaerobic inactivation and oxygen tolerance in a large series of NiFe hydrogenase mutants
Abbas Abou Hamdan et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)
Mechanistic insight into the blocking of CO diffusion in [NiFe]-hydrogenase mutants through multiscale simulation
Po-Hung Wang et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)
Carbon dioxide reduction to methane and coupling with acetylene to form propylene catalyzed by remodeled nitrogenase
Zhi-Yong Yang et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)
Kinetics and thermodynamics of gas diffusion in a NiFe hydrogenase
Jeremie Topin et al.
PROTEINS-STRUCTURE FUNCTION AND BIOINFORMATICS (2012)
Radical SAM-Dependent Carbon Insertion into the Nitrogenase M-Cluster
Jared A. Wiig et al.
SCIENCE (2012)
Hydrogenases and oxygen
Martin Tillmann Stiebritz et al.
CHEMICAL SCIENCE (2012)
Proton-Pumping Mechanism of Cytochrome c Oxidase
Shinya Yoshikawa et al.
ANNUAL REVIEW OF BIOPHYSICS, VOL 40 (2011)
Electron Transfer within Nitrogenase: Evidence for a Deficit-Spending Mechanism
Karamatullah Danyal et al.
BIOCHEMISTRY (2011)
On understanding proton transfer to the biocatalytic [Fe-Fe]H sub-cluster in [Fe-Fe] H2ases: QM/MM MD simulations
G. Hong et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2011)
Alternative photosynthetic electron transport pathways during anaerobiosis in the green alga Chlamydomonas reinhardtii
Anja Hemschemeier et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2011)
How does vanadium nitrogenase reduce CO to hydrocarbons
Ian Dance
DALTON TRANSACTIONS (2011)
Photolysis of Hi-CO Nitrogenase - Observation of a Plethora of Distinct CO Species Using Infrared Spectroscopy
Lifen Yan et al.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2011)
Nickel-Iron-Selenium Hydrogenases - An Overview
Carla S. A. Baltazar et al.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2011)
Carbon Monoxide Dehydrogenase Reaction Mechanism: A Likely Case of Abnormal CO2 Insertion to a Ni-H- Bond
Patricia Amara et al.
INORGANIC CHEMISTRY (2011)
Targeting Intermediates of [FeFe]-Hydrogenase by CO and CN Vibrational Signatures
Lian Yu et al.
INORGANIC CHEMISTRY (2011)
Tungsten and Molybdenum Regulation of Formate Dehydrogenase Expression in Desulfovibrio vulgaris Hildenborough
Sofia M. da Silva et al.
JOURNAL OF BACTERIOLOGY (2011)
Molybdenum Nitrogenase Catalyzes the Reduction and Coupling of CO to Form Hydrocarbons
Zhi-Yong Yang et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2011)
O2 Reactions at the Six-iron Active Site (H-cluster) in [FeFe]-Hydrogenase
Camilla Lambertz et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2011)
Mechanism of Proton Transfer in [FeFe]-Hydrogenase from Clostridium pasteurianum
Adam J. Cornish et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2011)
The mechanism of formate oxidation by metal-dependent formate dehydrogenases
Cristiano S. Mota et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2011)
Oxygen-Tolerant [NiFe]-Hydrogenases: The Individual and Collective Importance of Supernumerary Cysteines at the Proximal Fe-S Cluster
Michael J. Lukey et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Multiscale Simulation Reveals Multiple Pathways for H2 and O2 Transport in a [NiFe]-Hydrogenase
Po-hung Wang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Regioselectivity of H Cluster Oxidation
Marta K. Bruska et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Rates of Intra- and Intermolecular Electron Transfers in Hydrogenase Deduced from Steady-State Activity Measurements
Sebastien Dementin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Original Design of an Oxygen-Tolerant [NiFe] Hydrogenase: Major Effect of a Valine-to-Cysteine Mutation near the Active Site
Pierre-Pol Liebgott et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
The crystal structure of an oxygen-tolerant hydrogenase uncovers a novel iron-sulphur centre
Johannes Fritsch et al.
NATURE (2011)
Structural basis for a [4Fe-3S] cluster in the oxygen-tolerant membrane-bound [NiFe]-hydrogenase
Yasuhito Shomura et al.
NATURE (2011)
A unique iron-sulfur cluster is crucial for oxygen tolerance of a [NiFe]-hydrogenase
Tobias Goris et al.
NATURE CHEMICAL BIOLOGY (2011)
Characterization of a unique [FeS] cluster in the electron transfer chain of the oxygen tolerant [NiFe] hydrogenase from Aquifex aeolicus
Maria-Eirini Pandelia et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2011)
NifEN-B complex of Azotobacter vinelandii is fully functional in nitrogenase FeMo cofactor assembly
Jared A. Wiig et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2011)
Extending the Carbon Chain: Hydrocarbon Formation Catalyzed by Vanadium/Molybdenum Nitrogenases
Yilin Hu et al.
SCIENCE (2011)
Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor
Thomas Spatzal et al.
SCIENCE (2011)
X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor
Kyle M. Lancaster et al.
SCIENCE (2011)
Metabolic flexibility of sulfate-reducing bacteria
Caroline M. Plugge et al.
FRONTIERS IN MICROBIOLOGY (2011)
An alternative path for the evolution of biological nitrogen fixation
Eric S. Boyd et al.
FRONTIERS IN MICROBIOLOGY (2011)
[FeFe]-Hydrogenase Cyanide Ligands Derived From S-Adenosylmethionine-Dependent Cleavage of Tyrosine
Rebecca C. Driesener et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)
Hydrogenases from Methanogenic Archaea, Nickel, a Novel Cofactor, and H-2 Storage
Rudolf K. Thauer et al.
ANNUAL REVIEW OF BIOCHEMISTRY, VOL 79 (2010)
Inhibition of the [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F by carbon monoxide: An FTIR and EPR spectroscopic study
Maria-Eirini Pandelia et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2010)
Proton-Coupled Electron Flow in Protein Redox Machines
Jillian L. Dempsey et al.
CHEMICAL REVIEWS (2010)
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications
Jeffrey J. Warren et al.
CHEMICAL REVIEWS (2010)
Intermediates in the Catalytic Cycle of [NiFe] Hydrogenase: Functional Spectroscopy of the Active Site
Maria-Eirini Pandelia et al.
CHEMPHYSCHEM (2010)
The Crystal Structure of the [NiFe] Hydrogenase from the Photosynthetic Bacterium Allochromatium vinosum: Characterization of the Oxidized Enzyme (Ni-A State)
Hideaki Ogata et al.
JOURNAL OF MOLECULAR BIOLOGY (2010)
Two-Step Chronoamperometric Method for Studying the Anaerobic Inactivation of an Oxygen Tolerant NiFe Hydrogenase
Vincent Fourmond et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
[FeFe]-Hydrogenase Maturation: HydG-Catalyzed Synthesis of Carbon Monoxide
Eric M. Shepard et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Conformational Gating of Electron Transfer from the Nitrogenase Fe Protein to MoFe Protein
Karamatullah Danyal et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Membrane-Bound Hydrogenase I from the Hyperthermophilic Bacterium Aquifex aeolicus: Enzyme Activation, Redox Intermediates and Oxygen Tolerance
Maria-Eirini Pandelia et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Stepwise [FeFe]-hydrogenase H-cluster assembly revealed in the structure of HydAΔEFG
David W. Mulder et al.
NATURE (2010)
Relating diffusion along the substrate tunnel and oxygen sensitivity in hydrogenase
Pierre-Pol Liebgott et al.
NATURE CHEMICAL BIOLOGY (2010)
Nitrogen Fixation and Hydrogen Metabolism in Cyanobacteria
Hermann Bothe et al.
MICROBIOLOGY AND MOLECULAR BIOLOGY REVIEWS (2010)
The surprising diversity of clostridial hydrogenases: a comparative genomic perspective
Magdalena Calusinska et al.
MICROBIOLOGY-SGM (2010)
A Cell-Free Microtiter Plate Screen for Improved [FeFe] Hydrogenases
James A. Stapleton et al.
PLOS ONE (2010)
Development of an In Vitro Compartmentalization Screen for High-Throughput Directed Evolution of [FeFe] Hydrogenases
James A. Stapleton et al.
PLOS ONE (2010)
Vanadium Nitrogenase Reduces CO
Chi Chung Lee et al.
SCIENCE (2010)
Influence of the [2Fe]H Subcluster Environment on the Properties of Key Intermediates in the Catalytic Cycle of [FeFe] Hydrogenases: Hints for the Rational Design of Synthetic Catalysts
Maurizio Bruschi et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)
Mechanism of Mo-Dependent Nitrogenase
Lance C. Seefeldt et al.
ANNUAL REVIEW OF BIOCHEMISTRY (2009)
The Structure of the Active Site H-Cluster of [FeFe] Hydrogenase from the Green Alga Chlamydomonas reinhardtii Studied by X-ray Absorption Spectroscopy
Sven Stripp et al.
BIOCHEMISTRY (2009)
Activation of HydAΔEFG Requires a Preformed [4Fe-4S] Cluster
David W. Mulder et al.
BIOCHEMISTRY (2009)
Hydrogenase cluster biosynthesis: organometallic chemistry nature's way
Shawn E. McGlynn et al.
DALTON TRANSACTIONS (2009)
[NiFe] hydrogenases: structural and spectroscopic studies of the reaction mechanism
Hideaki Ogata et al.
DALTON TRANSACTIONS (2009)
Genome Sequence of Azotobacter vinelandii, an Obligate Aerobe Specialized To Support Diverse Anaerobic Metabolic Processes
Joao C. Setubal et al.
JOURNAL OF BACTERIOLOGY (2009)
Probing intermediates in the activation cycle of [NiFe] hydrogenase by infrared spectroscopy: the Ni-SIr state and its light sensitivity
Maria-Eirini Pandelia et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2009)
Spectroelectrochemical Study of the [NiFe] Hydrogenase from Desulfovibrio vulgaris Miyazaki F in Solution and Immobilized on Biocompatible Gold Surfaces
Diego Millo et al.
JOURNAL OF PHYSICAL CHEMISTRY B (2009)
Optimization of FeMoco Maturation on NifEN
Janice M. Yoshizawa et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)
Electrochemical Kinetic Investigations of the Reactions of [FeFe]-Hydrogenases with Carbon Monoxide and Oxygen: Comparing the Importance of Gas Tunnels and Active-Site Electronic/Redox Effects
Gabrielle Goldet et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)
Introduction of Methionines in the Gas Channel Makes [NiFe] Hydrogenase Aero-Tolerant
Sebastien Dementin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)
Structure-function relationships of anaerobic gas-processing metalloenzymes
Juan C. Fontecilla-Camps et al.
NATURE (2009)
Electron transfer in syntrophic communities of anaerobic bacteria and archaea
Alfons J. M. Stams et al.
NATURE REVIEWS MICROBIOLOGY (2009)
N-14 HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge
Alexey Silakov et al.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2009)
How oxygen attacks [FeFe] hydrogenases from photosynthetic organisms
Sven T. Stripp et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2009)
Stepwise formation of P-cluster in nitrogenase MoFe protein
Chi Chung Lee et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2009)
Unique features of the nitrogenase VFe protein from Azotobacter vinelandii
Chi Chung Lee et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2009)
Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models
Michael L. Singleton et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
Implications of a carboxylate-bound C-cluster structure of carbon monoxide dehydrogenase
Paul A. Lindahl
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
Xenon in and at the end of the tunnel of bifunctional carbon monoxide dehydrogenase/acetyl-CoA synthase
Tzanko I. Doukov et al.
BIOCHEMISTRY (2008)
Isolation and first EPR characterization of the [FeFe]-hydrogenases from green algae
Christina Kamp et al.
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2008)
Acetogenesis and the Wood-Ljungdahl pathway of CO2 fixation
Stephen W. Ragsdale et al.
BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS (2008)
Predicting the conformations of peptides and proteins in early evolution. A review article submitted to Biology Direct
E. James Milner-White et al.
BIOLOGY DIRECT (2008)
Shewanella oneidensis:: a new and efficient system for expression and maturation of heterologous [Fe-Fe] hydrogenase from Chlamydomonas reinhardtii
Kateryna Sybirna et al.
BMC BIOTECHNOLOGY (2008)
HydF as a scaffold protein in [FeFe] hydrogenase H-cluster biosynthesis
Shawn E. McGlynn et al.
FEBS LETTERS (2008)
Periplasmic nitrate reductase revisited:: a sulfur atom completes the sixth coordination of the catalytic molybdenum
Shabir Najmudin et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2008)
Tunnel mutagenesis and Ni-dependent reduction and methylation of the alpha subunit of acetyl coenzyme A synthase/carbon monoxide dehydrogenase
Xiangshi Tan et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2008)
Dithiomethylether as a ligand in the hydrogenase H-cluster
Arti S. Pandey et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Experimental approaches to kinetics of gas diffusion in hydrogenase
Fanny Leroux et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2008)
Structure of the α2ε2 Ni-dependent CO dehydrogenase component of the Methanosarcina barkeri acetyl-CoA decarbonylase/synthase complex
Weimin Gong et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2008)
A QM/MM study of proton transport pathways in a [NiFe] hydrogenase
Ignacio Fdez. Galvan et al.
PROTEINS-STRUCTURE FUNCTION AND BIOINFORMATICS (2008)
A natural choice for activating hydrogen (vol 321, pg 498, 2008)
F. A. Armstrong et al.
SCIENCE (2008)
The crystal structure of [Fe]-hydrogenase reveals the geometry of the active site
Seigo Shima et al.
SCIENCE (2008)
Proton pathways in a [NiFe]-hydrogenase: A theoretical study
Vitor H. Teixeira et al.
PROTEINS-STRUCTURE FUNCTION AND BIOINFORMATICS (2008)
Iron-sulfur protein folds, iron-sulfur chemistry, and evolution
Jacques Meyer
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2008)
Carbon dioxide activation at the Ni,Fe-cluster of anaerobic carbon monoxide dehydrogenase
Jae-Hun Jeoung et al.
SCIENCE (2007)
EPR characterization of the molybdenum(V) forms of formate dehydrogenase from Desulfovibrio desulfuricans ATCC 27774 upon formate reduction
Maria G. Rivas et al.
JOURNAL OF INORGANIC BIOCHEMISTRY (2007)
Molecular insights into nitrogenase FeMoco insertion -: The role of His 274 and His 451 of MoFe protein α subunit
Aaron W. Fay et al.
JOURNAL OF INORGANIC BIOCHEMISTRY (2007)
Alkyne substrate interaction within the nitrogenase MoFe protein
Patricia C. Dos Santos et al.
JOURNAL OF INORGANIC BIOCHEMISTRY (2007)
Occurrence, classification, and biological function of hydrogenases: An overview
Paulette M. Vignais et al.
CHEMICAL REVIEWS (2007)
[NiFe] and [FeFe] hydrogenases studied by advanced magnetic resonance techniques
Wolfgang Lubitz et al.
CHEMICAL REVIEWS (2007)
The electronic structure of the H-cluster in the [FeFe]-hydrogenase from Desulfovibrio desulfuricans:: A Q-band 57Fe-ENDOR and HYSCORE study
Alexey Silakov et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)
Structural insights into the active-ready form of [FeFe]-Hydrogenase and mechanistic details of its inhibition by carbon monoxide
Claudio Greco et al.
INORGANIC CHEMISTRY (2007)
Rapid and efficient electrocatalytic CO2/CO interconversions by Carboxydothermus hydrogenoformans CO dehydrogenase I on an electrode
Alison Parkin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)
P-cluster maturation on nitrogenase MoFe protein
Yilin Hu et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2007)
High-resolution structures of formate dehydrogenase from Candida boidinii
Katja Schirwitz et al.
PROTEIN SCIENCE (2007)
The alkaline solution to the emergence of life: Energy, entropy and early evolution
Michael J. Russell
ACTA BIOTHEORETICA (2007)
[FeFe] hydrogenases and their evolution: a genomic perspective
J. Meyer
CELLULAR AND MOLECULAR LIFE SCIENCES (2007)
Molecular insights into nitrogenase FeMo cofactor insertion:: the role of His 362 of the MoFe protein α subunit in FeMo cofactor incorporation
Yilin Hu et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2007)
Electrochemical investigations of the interconversions between catalytic and inhibited states of the [FeFe]-hydrogenase from Desulfovibrio desulfuricans
Alison Parkin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)
FeMo cofactor maturation on NifEN
Yilin Hu et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2006)
Nitrogenase Fe protein: A molybdate/homocitrate insertase
Yilin Hu et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2006)
Water-splitting chemistry of photosystem II
James P. McEvoy et al.
CHEMICAL REVIEWS (2006)
Molecular insights into nitrogenase FeMoco insertion -: TRP-444 of MoFe protein α-subunit locks FeMoco in its binding site
Yilin Hu et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2006)
Formate-reduced E-coli formate dehydrogenase H:: the reinterpretation of the crystal structure suggests a new reaction mechanism
Hans C. A. Raaijmakers et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2006)
Spectroelectrochemical characterization of the [NiFe] hydrogenase of Desulfovibrio vulgaris Miyazaki F
Caroline Fichtner et al.
BIOCHEMISTRY (2006)
Chance and design - Proton transfer in water, channels and bioenergetic proteins
Colin A. Wraight
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2006)
Resolving the CO/CN ligand arrangement in CO-inactivated [FeFe] hydrogenase by first principles density functional theory calculations
Silviu Zilberman et al.
INORGANIC CHEMISTRY (2006)
Changing the ligation of the distal [4Fe4S] cluster in NiFe hydrogenase impairs inter- and intramolecular electron transfers
S Dementin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)
Function of the tunnel in acetylcoenzyme A synthase/carbon monoxide dehydrogenase
XS Tan et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2006)
Catalysis by enzymes: The biological ammonia synthesis
B Hinnemann et al.
TOPICS IN CATALYSIS (2006)
Redox interaction of cytochrome c3 with [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F
N Yahata et al.
BIOCHEMISTRY (2006)
A single-crystal ENDOR and density functional theory study of the oxidized states of the [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F
M van Gastel et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2006)
The active site of the [FeFe]-hydrogenase from Desulfovibrio desulfuricans. II. Redox properties, light sensitivity and CO-ligand exchange as observed by infrared spectroscopy
W Roseboom et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2006)
The active site of the [FeFe]-hydrogenase from Desulfovibrio desulfuricans. 1. Light sensitivity and magnetic hyperfine interactions as observed by electron paramagnetic resonance
SPJ Albracht et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2006)
New insights into the mechanism of nickel insertion into carbon monoxide dehydrogenase:: analysis of Rhodospirillum rubrum carbon monoxide dehydrogenase variants with substituted ligands to the [Fe3S4] portion of the active-site C-cluster
WB Jeon et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2005)
Electron inventory, kinetic assignment (En), structure, end bonding of nitrogenase turnover intermediates with C2H2 and CO
HI Lee et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Life in hot carbon monoxide:: The complete genome sequence of Carboxydothermus hydrogenoformans Z-2901
M Wu et al.
PLOS GENETICS (2005)
Activation process of [NiFe] hydrogenase elucidated by high-resolution X-ray analyses: Conversion of the ready to the unready state
H Ogata et al.
STRUCTURE (2005)
Nitrogenase reactivity with P-cluster variants
YL Hu et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2005)
Nitrogenase complexes: Multiple docking sites for a nucleotide switch protein
FA Tezcan et al.
SCIENCE (2005)
Enlarging the gas access channel to the active site renders the regulatory hydrogenase HupUV of Rhodobacter capsulatus O2 sensitive without affecting its transductory activity
O Duché et al.
FEBS JOURNAL (2005)
Oxygen tolerance of the H2-sensing [NiFe] hydrogenase from Ralstonia eutropha H16 is based on limited access of oxygen to the active site
T Buhrke et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2005)
Variant MoFe proteins of Azotobacter vinelandii:: effects of carbon monoxide on electron paramagnetic resonance spectra generated during enzyme turnover
Z Maskos et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2005)
Structural differences between the ready and unready oxidized states of [NiFe] hydrogenases
A Volbeda et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2005)
The tunnel of acetyl-coenzyme a synthase/carbon monoxide dehydrogenase regulates delivery of CO to the active site
XS Tan et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Long-range electron transfer
HB Gray et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2005)
Sites for phosphates and iron-sulfur thiolates in the first membranes: 3 to 6 residue anion-binding motifs (nests)
EJ Milner-White et al.
ORIGINS OF LIFE AND EVOLUTION OF BIOSPHERES (2005)
Finding gas diffusion pathways in proteins: Application to O-2 and H-2 transport in Cpl [FeFe]-hydrogenase and the role of packing defects
J Cohen et al.
STRUCTURE (2005)
A glutamate is the essential proton transfer gate during the catalytic cycle of the [NiFe] hydrogenase
S Dementin et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2004)
Incorporation of either molybdenum or tungsten into formate dehydrogenase from Desulfovibrio alaskensis NCIMB 13491;: EPR assignment of the proximal iron-sulfur cluster to the pterin cofactor in formate dehydrogenases from sulfate-reducing bacteria
CD Brondino et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
The activation of the [NiFe]-hydrogenase from Allochromatium vinosum.: An infrared spectro-electrochemical study
B Bleijlevens et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
Substrate interaction at an iron-sulfur face of the FeMo-cofactor during nitrogenase catalysis
BM Barney et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2004)
Mechanism of primary proton transfer in bacteriorhodopsin
AN Bondar et al.
STRUCTURE (2004)
Crystallographic evidence for a CO/CO2 tunnel gating mechanism in the bifunctional carbon monoxide dehydrogenase/acetyl coenzyme A synthase from Moorella thermoacetica
A Volbeda et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
FTIR spectroelectrochemical study of the activation and inactivation processes of [NiFe] hydrogenases:: effects of solvent isotope replacement and site-directed mutagenesis
AL De Lacey et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
The path to the transition state in enzyme reactions: a survey of catalytic efficiencies
MG Snider et al.
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY (2004)
Evidence for a proton transfer network and a required persulfide-bond-forming cysteine residue in Ni-containing carbon monoxide dehydrogenases
EJ Kim et al.
BIOCHEMISTRY (2004)
Mo and W bis-MGD enzymes: nitrate reductases and formate dehydrogenases
JJG Moura et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
Trails of green alga hydrogen research - from Hans Gaffron to new frontiers
A Melis et al.
PHOTOSYNTHESIS RESEARCH (2004)
Wavelength dependence of the photo-induced conversion of the Ni-C to the Ni-L redox state in the [NiFe] hydrogenase of Desulfovibrio vulgaris Miyazaki F
C Fichtner et al.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2003)
Direct detection of a hydrogen ligand in the [NiFe] center of the regulatory H2-sensing hydrogenase from Ralstonia eutropha in its reduced state by HYSCORE and ENDOR spectroscopy
M Brecht et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Electron tunneling through proteins
HB Gray et al.
QUARTERLY REVIEWS OF BIOPHYSICS (2003)
Catalytic reduction of dinitrogen to ammonia at a single molybdenum center
DV Yandulov et al.
SCIENCE (2003)
Genomics insights into symbiotic nitrogen fixation
S Weidner et al.
CURRENT OPINION IN BIOTECHNOLOGY (2003)
Ni-Zn-[Fe4-S4] and Ni-Ni-[Fe4-S4] clusters in closed and open subunits of acetyl-CoA synthase/carbon monoxide dehydrogenase
C Darnault et al.
NATURE STRUCTURAL BIOLOGY (2003)
Single crystal EPR studies of the reduced active site of [NiFe] hydrogenase from Desulfiovibrio vulgaris Miyazaki F
S Foerster et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Photo-lability of CO bound to mo-nitrogenase from Azotobacter vinelandii
Z Maskos et al.
JOURNAL OF INORGANIC BIOCHEMISTRY (2003)
The tungsten-containing formate dehydrogenase from Methylobacterium extorquens AM1: Purification and properties
M Laukel et al.
EUROPEAN JOURNAL OF BIOCHEMISTRY (2003)
Catalytic synthesis of ammonia - A never-ending story?
R Schlogl
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)
Spectroscopic and kinetic characterization of active site mutants of Desulfovibrio fructosovorans Ni-Fe hydrogenase
AL DeLacey et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2003)
[Fe]-hydrogenases in green algae: photo-fermentation and hydrogen evolution under sulfur deprivation
M Winkler et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2002)
High-resolution crystallographic analysis of Desulfovibrio fructiosovorans [NiFe] hydrogenase
A Volbeda et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2002)
A Ni-Fe-Cu center in a bifunctional carbon monoxide dehydrogenase/acetyl-CoA synthase
TI Doukov et al.
SCIENCE (2002)
Structural studies of the carbon monoxide complex of [NiFe]hydrogenase from Desulfovibrio vulgaris Miyazaki F:: Suggestion for the initial activation site for dihydrogen
H Ogata et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)
Crystallographic analysis of the MoFe protein of nitrogenase from a nifV mutant of Klebsiella pneumoniae identifies citrate as a ligand to the molybdenum of iron molybdenum cofactor (FeMoco)
SM Mayer et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2002)
Nitrogenase MoFe-protein at 1.16 Å resolution:: A central ligand in the FeMo-cofactor
O Einsle et al.
SCIENCE (2002)
Gene sequence and the 1.8 Å crystal structure of the tungsten-containing formate dehydrogenase from Desulfolvibrio gigas
H Raaijmakers et al.
STRUCTURE (2002)
Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex
DV Yandulov et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)
Structure of a cofactor-deficient nitrogenase MoFe protein
B Schmid et al.
SCIENCE (2002)
Molecular basis of proton motive force generation:: Structure of formate dehydrogenase-N
M Jormakka et al.
SCIENCE (2002)
Reduction of short chain alkynes by a nitrogenase α-70Ala-substituted MoFe protein
SM Mayer et al.
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (2002)
Infrared studies of the CO-inhibited form of the Fe-only hydrogenase from Clostridium pasteurianum I:: Examination of its light sensitivity at cryogenic temperatures
ZJ Chen et al.
BIOCHEMISTRY (2002)
Iron hydrogenases - ancient enzymes in modern eukaryotes
DS Horner et al.
TRENDS IN BIOCHEMICAL SCIENCES (2002)
Interaction of acetylene and cyanide with the resting state of nitrogenase α-96-substituted MoFe proteins
PMC Benton et al.
BIOCHEMISTRY (2001)
Life on carbon monoxide:: X-ray structure of Rhodospirillum rubrum Ni-Fe-S carbon monoxide dehydrogenase
CL Drennan et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2001)
Crystal structure of a carbon monoxide dehydrogenase reveals a [Ni-4Fe-5S] cluster
H Dobbek et al.
SCIENCE (2001)
Classification and phylogeny of hydrogenases
PM Vignais et al.
FEMS MICROBIOLOGY REVIEWS (2001)
Genetics and genomics of root symbiosis
J Stougaard
CURRENT OPINION IN PLANT BIOLOGY (2001)
Relativistic DFT calculations of the paramagnetic intermediates of [NiFe] hydrogenase. Implications for the enzymatic mechanism
M Stein et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Tungsten-containing formats dehydrogenase from Desulfovibrio gigas:: metal identification and preliminary structural data by multi-wavelength crystallography
H Raaijmakers et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2001)
Mossbauer characterization of the iron-sulfur clusters in Desulfovibrio vulgaris hydrogenase
AS Pereira et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Stereospecificity of acetylene reduction catalyzed by nitrogenase
PMC Benton et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Crystallographic and FTIR spectroscopic evidence of changes in Fe coordination upon reduction of the active site of the Fe-only hydrogenase from Desulfovibrio desulfuricans
Y Nicolet et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Mechanistic features and structure of the nitrogenase α-Gln195 MoFe protein
M Sorlie et al.
BIOCHEMISTRY (2001)
Hydrogen production by biological processes: a survey of literature
D Das et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2001)
[NiFe] hydrogenase from Desulfovibrio desulfuricans ATCC 27774: gene sequencing, three-dimensional structure determination and refinement at 1.8 angstrom and modelling studies of its interaction with the tetrahaem cytochrome c(3)
PM Matias et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2001)
Differential effects on N2 binding and reduction, HD formation, and azide reduction with α-195His- and α-191Gln-substituted MoFe proteins of Azotobacter vinelandii nitrogenase
K Fisher et al.
BIOCHEMISTRY (2000)
Insights into nucleotide signal transduction in nitrogenase: Protein with MgADP bound
SB Jang et al.
BIOCHEMISTRY (2000)
Competitive substrate and inhibitor interactions at the physiologically relevant active site of nitrogenase
J Christiansen et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2000)
FTIR characterization of the active site of the Fe-hydrogenase from Desulfovibrio desulfuricans
AL De Lacey et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Iron hydrogenases and the evolution of anaerobic eukaryotes
DS Horner et al.
MOLECULAR BIOLOGY AND EVOLUTION (2000)
Azotobacter vinelandii nitrogenases with substitutions in the FeMo-cofactor environment of the MoFe protein:: Effects of acetylene or ethylene on interactions with H+, HCN, and CN-
K Fisher et al.
BIOCHEMISTRY (2000)
Mossbauer study of the MoFe protein of nitrogenase from Azotobacter vinelandii using selective 57Fe enrichment of the M-centers
SJ Yoo et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Photochemistry at the active site of the carbon monoxide inhibited form of the iron-only hydrogenase (CpI)
BJ Lemon et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Isolation and characterization of an acetylene-resistant nitrogenase
J Christiansen et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2000)
Azotobacter vinelandii nitrogenases containing altered MoFe proteins with substitutions in the FeMo-cofactor environment:: Effects on the catalyzed reduction of acetylene and ethylene
K Fisher et al.
BIOCHEMISTRY (2000)
Channeling of carbon monoxide during anaerobic carbon dioxide fixation
J Seravalli et al.
BIOCHEMISTRY (2000)
Sustained photobiological hydrogen gas production upon reversible inactivation of oxygen evolution in the green alga Chlamydomonas reinhardtii
A Melis et al.
PLANT PHYSIOLOGY (2000)