Journal
CHEMICAL ENGINEERING RESEARCH & DESIGN
Volume 186, Issue -, Pages 362-373Publisher
ELSEVIER
DOI: 10.1016/j.cherd.2022.07.049
Keywords
Biochars; Adsorption mechanism; Antibiotic; Density functional theory
Categories
Funding
- National Natural Science Foundation of China [21978047, 21776046]
- Fundamental Research Funds for the Central Universities [2242020K40033]
- Six Talent Peaks Project in Jiangsu Province [XCL-079]
Ask authors/readers for more resources
In this study, high-performance activated carbons with high specific surface area were achieved using sesame straw as a precursor. The addition of co-activators further enhanced the pore structure and adsorption performance of the activated carbons. The adsorption mechanism of antibiotics on these activated carbons was found to involve electrostatic interaction, hydrogen bond, and pi-pi interaction.
High-performance activated carbons are crucial for adsorbing antibiotics in water environment. In this work, amorphous porous biochars (APBCs) with high specific surface area (935 m2 center dot g-1) were achieved by using sesame straw. Compared with the conventional biochars precursor, sesame straw with the advantages of rich resources and low price is more economical and environmentally friendly. Moreover, KOH and Ca(OH)2 were selected as co-activators, which characterization results revealed that co-activators significantly increased the coarseness of activated carbon surface and enlarged pore structure. In addition, the adsorption mechanism of norfloxacin (NOR), ciprofloxacin (CIP) and enrofloxacin (ENR) on APBCs were further investigated by experiments and density functional theory (DFT) calculations. The results discovered that pseudo second-order kinetics and Sips model followed the adsorption experiment data, implying that the adsorption process was heterogeneous and multilayer. And the interactions between APBCs and antibiotics were electrostatic interaction, hydrogen bond and pi-pi interaction, which were conducive to chemical adsorption. (c) 2022 Institution of Chemical Engineers. Published by Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available