4.7 Article

Unprecedented continuous elastic foam-bed reactor for CO2 capture

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 452, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2022.138604

Keywords

Elastic foam -bed reactor; Mass transfer intensification; Carbonic anhydrase; Carbon capture and storage

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An elastic foam-bed reactor based on open-cell polymer foams was designed to enhance gas-liquid mass transfer of CO2 through compression/decompression cycles. The cycles, ensured by a crankshaft, require low additional electric power (<50 Watts) but significantly improve the mass transfer by one order of magnitude compared to fixed foam-bed reactor. Carbonic anhydrase-supported foam, using a supramolecular hydrogel for continuous applications, improves CO2 capture.
Open-cell polymer foams are memory shape materials with remarkable transport properties. We have designed an elastic foam-bed reactor based on these features to intensify gas-liquid mass transfer of CO2 through in situ foam compression/decompression cycles. The cycles are ensured by a crankshaft and only a low additional electric power (<50 Watts) is required under upflow co-current conditions in order to improve the mass transfer by one order to magnitude compared to fixed foam-bed reactor (i.e. without cycles). CO2 capture is improved thanks to carbonic anhydrase-supported foam (1.3 mg of enzyme per cm3 of foam) using a supramolecular hydrogel for continuous applications.

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