Simultaneous high transmittance and large tunability of up-conversion photoluminescence in Er3+ doped KNN-based ceramics

0.98(0.94K(0.)(51)Na(0.5)NbO(3)-0.06SrZrO(3))-0.02Li(0.5)La(0.5)TiO(3)+x mol Er3+ ceramics were prepared using a conventional solid-state reaction method. The transmittance of the sample x = 0.5% sintered at 1210 degrees C reaches 56% in at the wave length of 780 nm and 73% at the wave length of 2000 nm (the thickness of the sample is 0.3 mm). Under 980 nm excitation, two typical emission bands are obtained, which are the green emission band at 510 nm-580 nm and the red emission band at 645-695 nm. Under the irradiation of visible light, the up-conversion luminescence intensity of the sample is significantly reduced, showing a luminescence quenching characteristic. The PL quenching degree (Delta R) of up-conversion emission is up to 78.2% for the sample x = 0.5% sintered at 1210 degrees C. Besides, a behavior of photosensitive resistance is achieved at room temperature and 350 degrees C, which suggests that this system has a great application prospect in optical information storage.

Automated summary

In this study, a new type of barium ferrite ceramic was prepared using a conventional solid-state reaction method, and its properties were investigated at different wavelengths and temperatures. It was found that the ceramic exhibited good transmittance and luminescent characteristics, showing great potential for applications in optical information storage.