4.7 Article

Microstructure, mechanical, tribological, and oxidizing properties of AlCrSiN/AlCrVN/AlCrNbN multilayer coatings with different modulated thicknesses

Journal

CERAMICS INTERNATIONAL
Volume 48, Issue 22, Pages 32973-32985

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.07.228

Keywords

AlCrSiN; AlCrVN; AlCrNbN multilayer coatings; Modulated thickness; Mechanical properties; Elemental diffusion; Wear resistance; Oxidation resistance

Funding

  1. Natural Science Foundation of Hunan Province [2022JJ50009]
  2. National Natural Science Foundation of China [51971190]
  3. Research Start-up fund project of Xiangtan University [KZ08075]
  4. school-enterprise cooperation project [KH03113]
  5. Zhuzhou Huarui Precision Cutting Tools Co., Ltd.

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In this study, the microstructure, mechanical, tribological, and oxidizing properties of AlCrSiN/AlCrVN/AlCrNbN multilayer coatings were investigated. The results showed that decreasing the modulation thickness of the multilayer coatings led to refined grains, improved mechanical properties, reduced wear rate, and enhanced high-temperature oxidation resistance.
Multilayer structure design is one of the most promising methods for improving the comprehensive performance of AlCrN-based hard coatings applied to cutting tools. In this study, four types of AlCrSiN/AlCrVN/AlCrNbN multilayer coatings, with different modulated thicknesses, were deposited to investigate their microstructure, mechanical, tribological, and oxidizing properties. All multilayer coatings exhibited grain growth along the crystallographic plane of (200) with a NaCl-type face-centered cubic (FCC) structure. The results show that, as the modulation thickness decreases from -35 nm to -10 nm, (1) the grain refinement effect is increasingly evident; (2) all multilayer coatings show a hardness of >30 GPa and an elastic modulus of >300 GPa. Both the ability to resist elastic strain to failure and the plastic deformation of multilayer coatings increase. In addition, their resistance to cracking reduces; (3) the wear rates of these multilayer coatings reduce successively from 1.78 x 10-16 m3 N-1 m- 1 to 7.7 x 10-17 m3 N-1 m- 1. This is attributed to an increase in self-lubricating VOx and a decrease in adhesives from the counterparts; (4) the best high-temperature oxidation resistance was obtained for the multilayer coating with a modulated thickness of -15 nm.

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