TiO2 Supported RuRe Nanocatalysts for Soot Oxidation: Effect of Re and the Support Nature

Catalytic combustion of hazardous particulate matter (soot) generated by automobile engines is a primary method of their elimination. Ruthenium-based catalysts are a promising alternative for traditional noble metal (Pt, Pd) based systems; however, their relatively poor thermal stability hinders wide applications. In this study, we synthesized a novel, highly active, and stable catalyst for soot oxidation containing bimetallic RuRe nanoparticles supported on TiO2. The RuRe NPs were synthesized by colloidal, microwave-assisted polyol method and deposited on rutile or anatase TiO2. The effect of rhenium content and the nature of TiO2 support on the performance of RuRe nanoparticles (NPs) in the soot oxidation under air atmosphere was investigated. Bimetallic RuRe/TiO2 nanocatalysts exhibited higher activity in the soot oxidation than Ru/TiO2 systems, and the rutile supported 2 wt% Ru-0.4 wt% Re nanocatalyst (Ru/Re atomic ratio of 9:1) showed the best catalytic performance (T-50 =340 degrees C and T-90 < 400 degrees C). All studied nanocatalysts were stable under reaction conditions in the consecutive catalytic tests. The exceptional catalytic performance of bimetallic RuRe NPs is explained by the synergy effect between ruthenium, rhenium, and TiO2. [GRAPHICS] .

Automated summary

A novel bimetallic RuRe/TiO2 nanocatalyst was synthesized and demonstrated to exhibit high catalytic activity and stability in soot oxidation. The performance of the nanocatalyst can be further improved by adjusting the TiO2 support and rhenium content.