Mesoporous Ce-Fe-Ni nanocomposites encapsulated in carbon-nanofibers: Synthesis, characterization and catalytic behavior in oxygen evolution reaction

Ceria-iron oxide mesoporous materials with Fe:Ce molar ratio of 5:5 and 9:1 were synthesized by hydrothermal method using CTAB as a template and subsequently modified with NiO (molar ratio Ni:Fe = 1:2) by incipient wetness impregnation technique. In order to increase the electro-capacitive properties and reduce the intrinsic impedance of the metal oxides, the samples were consecutively modified by reduction in hydrogen to obtain highly dispersed Ni-Fe alloys into ceria matrix. By exploiting the high permeability of carbon inside ferrous alloys, the metal phase has been further modified into ferrous carbides and metal alloys encapsulated within carbon nanofibers. For this purpose, a reaction, already widely studied for the production of hydrogen, was used, that is the decomposition of methanol vapors. In fact, this decomposition, in addition to producing syn-gas and methane, changes the catalysts in use through a chemical vapor deposition-carbon coating process. This fact, has been used by us to demonstrate how the newly obtained metal-carbon nanocomposites can be used for electrocatalytic purposes. The modified phases of the two molar ratios of the Fe-Ni-Ce catalysts were tested in the Oxygen Evolution Reaction (OER) in an alkaline environment (1 M KOH), showing a satisfactory and progressive increase in activity and a surprising decrease in the overpotential at 10 mA/cm2 of current density. The morphological, textural and physicochemical properties of the samples were characterized in details by XRD, N2- physisorption, TG-TPO, TEM, EDX, FTIR, XPS, Raman and Moessbauer spectroscopies.

Automated summary

Ceria-iron oxide mesoporous materials were modified with Ni-Fe alloys and further transformed into ferrous carbides and metal alloys encapsulated within carbon nanofibers. The modified phases showed high electrochemical activity and low overpotential in the Oxygen Evolution Reaction. The morphological, textural and physicochemical properties of the samples were characterized in detail.