4.8 Article

Ni/Ni3ZnC0.7 modified alginate-derived carbon composites with porous structures for electromagnetic wave absorption

Journal

CARBON
Volume 200, Issue -, Pages 166-177

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2022.07.075

Keywords

Alginate; Biomass; Porous carbon; Electromagnetic wave absorption

Funding

  1. National Key Research and Development Project [2019YFC0312102, 2019YFC0312101]
  2. NSFC Shandong Joint Fund [U1706225]
  3. MacDiarmid Institute for Advanced Materials and Nano-technology
  4. Dodd Walls Centre for Photonic and Quantum Technologies

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Ni/Ni3ZnC0.7 modified alginate-derived carbon composites were successfully prepared by constructing a Ni2+-Zn2+-alginate gel, followed by freeze-drying and carbonization processes, showing improved EMW absorption properties with a maximum reflection loss of -40.2 dB and an effective absorption bandwidth of 5.4 GHz.
Electromagnetic wave (EMW) absorption materials with both high-performance and low-cost are demanded to reduce unwanted noise at microwave communication frequencies. Herein, Ni/Ni3ZnC0.7 modified alginate -derived carbon (Ni/Ni3ZnC0.7/C) composites were successfully prepared by constructing a Ni2+-Zn2+-alginate gel, followed by freeze-drying and carbonization processes. The co-introduction of nickel and zinc greatly improved EMW absorption properties. By adjusting the amounts of Ni2+ and Zn2+ ions, Ni/Ni3ZnC0.7/C composites with excellent impedance matching and EMW absorption performance were realized, evidenced by a maximum reflection loss of-40.2 dB (14.8 GHz, 2.0 mm) and an effective absorption bandwidth of 5.4 GHz (12.6-18.0 GHz, 2.0 mm). This work provides a very simple and green strategy for designing lightweight and high-performance EMW absorbers offering considerable potential for practical applications.

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