4.7 Review

Layered materials as nanocontainers for active corrosion protection: A brief review

Journal

APPLIED CLAY SCIENCE
Volume 225, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.clay.2022.106537

Keywords

Clay minerals; Layered double hydroxides; Layered hydroxide salts; Conversion coatings; Active corrosion protection; Corrosion inhibitors

Funding

  1. Coordena?a?o de Aperfei?oa-mento de Pessoal de N?vel Superior - Brazil (CAPES) [001]
  2. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brazil (CAPES) [001, C.E.B.M.: 303126/2019-1]
  3. Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [001, 88887.468259/2019-00]
  4. national funds through the FCT/MEC [F.W.: 300988/2019-2, UIDB/50011/2020]
  5. FEDER
  6. [UIDP/50011/2020]

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In recent years, layered materials have been widely used as nanocontainers for corrosion inhibitors on metallic surfaces. These materials have the advantage of releasing corrosion inhibitors and capturing aggressive species. The versatility of intercalating different corrosion inhibitors and synthesizing various layered materials allows for the production of efficient protective systems.
Over the past years, the use of layered materials such as clay minerals, layered double hydroxides, and layered hydroxide salts, as nanocontainers of corrosion inhibitors has grown, and these materials have proved to be very advantageous to improve the corrosion protection of metallic surfaces. The layered materials are especially advantageous for this application due to their capacity of not only releasing corrosion inhibitors on-demand to protect the metal but also capturing ionic aggressive species from the medium. The diversity of corrosion inhibitors species that can be intercalated in the interlayer space of these materials and the possibility to synthesize different layered materials (composition, structure, and morphology), using different methods, provide a high versatility to produce efficient protective systems, which are elucidated and discussed in this review. Moreover, a section on future perspectives is presented, indicating promising and still underexplored possibilities for future development trends in using layered materials for corrosion protection applications.

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